Organic Flashcards
Hydrocarbon
A compound containing only the elements hydrogen and carbon
Saturated
An organic compound in which all the bonds are single bonds
Homologous series
Series of organic compounds that have the same general formula, similar chem reactions abs where each member differs from the next by a -CH2- group
Unsaturated
An organic compound that contains a carbon-carbon double bond
General formula
A formula that states the ratio of atoms of each element in the formula of every compound in a particular homologous series
Isomerism
Compounds that have same molecular formula but diff displayed formula
Diff compounds called isomers
Alkanes
CnH2n+2
H | H-C-H | H
Methane
CH4
Ethane
C2H6
Propane
C3H8
Butane
C4H10
Pentane
C5H12
Isomers of butane
Methyl butane (one strand off)
Isomers of propane
Methyl propane
Dimethylpropane
Combustion of Alkanes
Burn w oxygen when heated in air
Plentiful supply= co2 + h2o
Insufficient supply = co + h20
(Carbon monoxide)
Poisonous
Reduces capacity of the blood to carry oxygen
Alkanes and bromine
Methane and bromine react together in UV light to form bromomethane
Substitution reaction- one atom in methane replaced with an atom of bromine
CH4 + Br2 -> CH3Br + HBr
Alkenes
CnH2n
H. H \ / C=C / \ H H
Ethene
C2H4
Propene
C3H6
Butene
C4H8
Pentene
C5H10
Isomers for C4H8
But-1-ene
But-2-ene
Methylpropene
Addition reactions
With halogens
Bromine can be added into an Alkene and will add across the double bond to form dibromoethane
C2H4 + Br2 -> C2H4Br2
Can be used to test for the presence of a carbon-carbon double bond
decolorisation of bromine
Ethanol method 1
Fermentation.
Dissolve starch or sugar in water and add yeast
Leave mixture to ferment at 25-40*c in absence of air
Filter off excess yeast to obtain dilute solution of ethanol
If ethanol content is above 15% then yeast will be killed
More conc solution needs to be distilled
C6H12O6 -> 2C2H5OH + 2CO2
Ethanol method 2
Direct hydration of Ethene
A mixture of Ethene and steam is passed over phosphoric acid catalyst at a temp of 300*c and 60-70 atmospheres of pressure
Ethanol is condensed as a liquid
Ethene required is taken from crud oil
C2H4 + H2O -> C2H5OH
Comparing methods of ethanol manufacturing
F Uses renewable resources Batch process V slow process Produces dilute solution Low temps required
H of e Non renewable resources(no more crude oil is a danger) Continuous process Fast process Produces pure ethanol High temps and pressures - costly
Combustion of ethanol
Burns w oxygen when heated in air
Can be used as fuel
C2H5OH + 3O2 -> 2CO2 + 3H2O
Dehydration of ethanol
Can be dehydrated by passing ethanol vapour over hot aluminium oxide which acts as a catalyst
C2H5OH -> C2H4 + H2O
Can be used to manufacture Ethene for production of polyethene
Most Ethene made from cracking crude oil fractions