Practice Questions - Week 6 - Carbohydrates Flashcards
Haworth projection formulas
a) are representations of the cyclic form of sugars
b) can show the distinction between the alpha and beta anomers
c) both of the above
d) neither of the above
c)
Which of the following monosaccharides is a ketose?
a) glucose
b) fructose
c) galactose
d) mannose
b)
T/F: A hemiacetal is a cyclic structure of a ketose
False
(A hemiacetal is a cyclised aldose structure; a hemiketal is a cyclised ketose)
It the open-chain form of a sugar, which carbon becomes the anomeric carbon in the cyclic form?
a) the carbonyl carbon
b) the highest numbered chiral centre
c) the highest numbered carbon
d) it depends on the individual sugar
a) the carbonyl carbon
T/F: A furanose is a sugar that contains a five-membered ring as part of its cyclic structure.
True
The alpha and beta forms of the same sugar are called
a) epimers
b) diastereoisomers
c) enatiomers
d) anomers
d)
Glycosidic linkages between monosaccharide units may vary based on
a) the anomeric form of the cyclic structure, that is the alpha or beta
b) which -OH group is involved
c) both of the above
d) none of the above
c)
T/F: Linear polymers are more water-soluble than branched ones
False
(Cellulose is a linear polymer and is less water soluble than branched starch)
T/F: Branched polymers have one non-reducing end, and many reducing ends
False
(Branched polymers have several non-reducing ends, one in each branch)
Which of the following molecules have the highest degree of alpha[1-6] branching linkages
a) Amylose
b) Amylopectin
c) Starch
d) Glycogen
d)
Glycoproteins:
a) are involved in the metabolism of sugars
b) are proteins covalently bound to sugars
c) occur in the bloodstream of diabetics
d) are mainly found in the cytosolic leaflet of the cell membrane
b)
When two carbohydrates are epimers:
a) one is a pyranose, the other a furanose.
b) one is an aldose, the other a ketose.
c) they differ in the number of carbons.
d) they differ only in the configuration around one carbon atom.
d)
(Epimers differ only in the configuration around one carbon atom. Please note: the term anomer also refers to monosaccharides that are epimers)
Which of the following statements about starch and glycogen is false?
a) Amylose is unbranched; amylopectin and glycogen contain many (α1→ 6) branches.
b) Both are homopolymers of glucose.
c) Both starch and glycogen are stored intracellularly as insoluble granules.
d) Both serve primarily as structural elements in cell walls.
e) Glycogen is more extensively branched than starch.
d)
(Starch and glycogen serve as energy storage. Cellulose is the primary structural carbohydrate in plant cell walls, chitin and glucans in fungi, and peptidoglycans in prokayotes)
The preferred energy source of the brain is ________. Why?
fructose
glucose
mannose
glycogen
glucose
(Glucose is virtually the sole fuel for the human brain, except during prolonged starvation. The brain lacks fuel stores and hence requires a continuous supply of glucose. It consumes about 120 g daily, which corresponds to an energy input of about approx. 1760 kJ, accounting for some 60% of the utilization of glucose by the whole body in the resting state)
The most abundant organic substance on earth is __________. Why?
cellulose
starch
chitin
sucrose
Cellulose
(Cellulose is the most abundant organic polymer on Earth. Cellulose is an important structural component of the primary cell wall of green plants, many forms of algae and the oomycetes. Some species of bacteria secrete it to form biofilms)