Polysaccharides and Lipids Flashcards
4 Classes of Macromolecules?
- Carbohydrates
- Lipids
- Proteins
- Nucleic Acids
How are Macromolecules Assembled?
Dehydration (or Condensation) Rxns
How are Macromolecules Broken Down
Hydrolysis Rxns
Carbohydrates Function?
Energy source and structural support.
Structural: Beta glycosidic linkage
-Cellulose : (cell walls of plants)
-Chitin : (structural polysaccharide in animals and fungi)
Storage: alpha glycosidic linkage
-Starch (plants)
-Glycogen (animals)
How are monosaccharides linked?
Via a glycosidic bond, which is a covalent bond and formed through a dehydration reaction.
Starch
Storage polysaccharide in plants
-unbranched: amylose
-branched: amylopectin
Alpha glycosidic bond linkages
Glycogen
Storage polysaccharide in animals
-stored in liver and muscle cells
Hydrolysis of this polysaccharide releases glucose when demand of sugar increases
Alpha glycosidic linkages
Cellulose
Structural Polysaccharide of plants
Higher stacking due to less branching (harder to breakdown)
Beta glycosidic linkages
Chitin
Structural polysaccharide in animals and fungi
-How arthropods (insects, spiders, crustaceans) build their exoskeleton
Beta glycosidic linkages
Clicker:
You are studying a polysaccharide that contains unbranched B-glycosidic linkages and cannot be digested by humans. Which polysaccharide are you studying?
a. Cellulose
b. Amylose
c. Amylopectin
d. Glycogen
a. Cellulose
Biological Functions of Lipids?
-energy storage
-thermal insulation
-hormone signaling
-membrane fluidity
Lipid Characteristics
-Non-polar
-Hydrophobic
-Lipid chains held together via van der Waals force (stacking of lipid tails)-> these aren’t polymers because subunits aren’t covalently bonded. But LDF’s are additive.
How are triglycerides formed?
Condensation (or dehydration) reaction
-ester bond formation
Saturated Fat
No double bonds in hydrocarbon chain
Unsaturated Fat
Double bonds in h-carbon chain
Cis conformation=naturally occurring