Polymerisation Flashcards
Polymerisation
Is the joining up of lots of little molecules called monomers, to form a big molecule called a polymer
Addition polymerisation
Is when alkenes add together to form the polymer. Only one product if formed
Monomer
A molecule that can combine with others to form a polymer
Polymer
A large molecule made up of linking monomers
Conditions for polymerisation
Heat
High pressure
An indicator
Used of polyethene
Low density- plastic bags
High density- plastic bottles
Ethene
Polyethlene
C2H4
Plastic bags and water bottles
Propene
Polypropene
C3H5
Packaging, roads, plastic bags
Chloroethene
Polychloroethene
C2H3Cl
Glue, plastic sheets, window frames
Styrene
Polystyrene
C2H3O
Cups, packaging
What happens when we throw away plastics
- landfill: can create lechate which poisons ecosystems
- plastic washes away to sea and is harmful to animals as they digest it and die. Sea pollution affects the food chain. An example of this is the great pacific garbage patch
Solutions for problems with ecosystems
When we reducen this doesn’t occur, the plastic is compressed and able to be reused
Why is polypropene stronger that polyethene
Because it contains more hydrogen to carbon bonds and it is therefore harder to break down
Dynamic equilibria eq
A + 2B ->
When a reaction has reached equilibrium
It has reached a state of balance. The overall amount of products and reactants stay constant
For a reaction in dynamic equilibrium
The rate of the forward reaction is equal to the rate or reversabke reaction
Le chatelier’s principle
If you apply a change to an equilibrium the reaction move in the direction to oppose that change
Changes in the equilibrium include
- increasing or decreasing the concentrations of substances present
- changing temp
- changing the pressure
Forward reaction is endothermic
Temp increasing, moves to the right, yield increases
Temp decreasing, moves to the left, yield decreases
Delta H= positiVe
Forward reaction is exothermic
Temp increases, equilibrium moves left, yield decreases
Temp descreases, equilibrium moves to the right, yield increases
Oh= negative
Concentration
Increasing the concentration of a reactant leaves equilibrium to the right
Increasing he yield of a product
Decreasing the concentration of a product moves equilibrium to the right
Increasing the yield of the product
Pressure
Increasing the pressure favours the side of the least number of gaseous molecules ( C+D)
Decreasing the pressure favours the side with the most gaseous molecules (a+2B)
Adding a catalyst…
Speeds up both the forward and the reverse reaction, so has no effect on the yield obtained from the reaction
Heating hydrated copper (ll) sulphate
Forward reaction with heating
CuSo4 . 5H20 —-> CuSo4 +5H2
Blue…. white
Back reaction of heating copper (ll) sulphate, one adittion with water
CuSo4 + 5H20 —-> CuSo4 . 5H2
White…. blue
Reversible reaction heating hydrated copper (ll) sulphate
CuSo4 . 5H20 CuSo4 +5H20
Heating ammonium chloride forward reaction with heating
NH4Cl —-> NH3 + HCl
White solid….. ammonia
Heating ammonium chloride reversible reaction
NH4Cl — NH3 + HCl
Back reaction on addition of H20 hearing ammonium chloride
NH3 + HCl —-> NH4Cl