Polarity Flashcards

1
Q

What determines how substances interact with each other?

A

polarity

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2
Q

Are polar bonds necessary for a molecule to be polar?

A

yes, but they’re not sufficient

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3
Q

What does a molecule also need in order for it to be polar?

A

needs to have a net dipole moment

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4
Q

What is a net dipole moment?

A

when there is an overall partial positive charge on one end of the molecule and a partial negative charge on the other end of the molecule

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5
Q

What is no net dipole moment?

A

Pulling of the forces cancel each other (nonpolar)

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6
Q

What is the polarity, basis of cancelation, and net dipole moment of linear geometry?

A

nonpolar
cancels out
no net dipole moment

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7
Q

What is the polarity, basis of cancelation, and net dipole moment of bent geometry?

A

polar
does not cancel out because of asymmetry
net dipole moment

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8
Q

What is the polarity, basis of cancelation, and net dipole moment of trigonal planar geometry?

A

nonpolar
cancels out
no net dipole moment

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9
Q

What is the polarity, basis of cancelation, and net dipole moment of tetrahedral geometry?

A

nonpolar
cancels out
no net dipole moment

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10
Q

What is the polarity, basis of cancelation, and net dipole moment of trigonal pyramidal geometry?

A

polar
does not cancel out
net dipole moment

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11
Q

What do lone pairs on an the central atom affect?

A

polarity and could potentially have a net dipole moment

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12
Q

Does asymmetry make a difference in identifying polarity?

A

yes, due to the force on a central atom with lone pairs

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13
Q

What is symmetry?

A

Pulling of the forces are even when there is no lone pair on the central atom

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14
Q

What plane is nonpolar in?

A

same plane

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15
Q

What plane is polar in?

A

not in same plane (asymmetric)

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16
Q

What does a molecule need in order to be polar?

A

polar bonds and a net dipole moment

17
Q

How do you know if a molecule has polar bonds?

A

If the difference in electronegativity for the atoms in a bond is greater than 0.5

18
Q

What kind of bond is it when ∆electronegativity is below 0.5?

A

nonpolar covalent bond

19
Q

What kind of bond is it when ∆electronegativity is between 0.5 and 2?

A

polar covalent bond

20
Q

What kind of bond is it when ∆electronegativity is above 2?

A

fully polar

21
Q

Can a molecule be polar if it has no net dipole moment?

22
Q

Do PFAs molecules have net dipole moments?

A

no, therefore is nonpolar

23
Q

What does intramolecular mean?

A

within molecule

24
Q

What does intermolecular mean?

A

between molecules

25
What are london dispersion forces?
attraction between two temporary, instantaneous, non-permanent dipoles (temporary)
26
What is dipole-dipole attraction?
attraction between a partially positive portion of one molecule and partially negative portion of a different molecule
27
What is the only interaction available for nonpolar molecules?
london dispersion forces
28
How strong are london dispersion forces?
fleeting and weak
29
How strong are dipole-dipole forces?
intermediate strength
30
What kind of bond do you need for a dipole-dipole attraction to exist?
polar bond
31
What will there be in a dipole-dipole attraction?
attraction or repulsion
32
What is hydrogen bonding responsible for?
water behavior+properties
33
What is a special case of dipole-dipole interaction?
hydrogen bonding
34
What elements are reserved for hydrogen bonding?
when hydrogen is bonded to nitrogen, oxygen, or fluorine
35
How strong are hydrogen bonds?
strong interaction
36
Are london dispersion forces intramolecular or intermolecular?
intermolecular
37
Are hydrogen bondings intramolecular or intermolecular?
intermolecular
38
Are dipole-dipole attractions intramolecular or intermolecular?
intermolecular