Kinetic Molecular Theory Flashcards

1
Q

Does boron follow octet rule?

A

no

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2
Q

Why doesn’t boron follow octet rule?

A

doesn’t want to give up electrons
doesn’t want to look like a noble gas
happy with sharing electrons with hydrogen and having 6 electrons

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3
Q

Why are expanded octets allowed to exist?

A

elements in the third period and beyond on the periodic table have available d-orbitals in their valence shell, which can accommodate additional electrons beyond the typical eight, allowing them to form more bonds and exceed the octet rule

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4
Q

Why are expanded octets called expanded octets?

A

they go into 3d orbitals

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5
Q

Are reactivity and geometry connected?

A

yes

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6
Q

What does stable mean?

A

won’t react easily

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7
Q

What does unstable mean?

A

will react easily

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8
Q

What is the kinetic molecule theory?

A

kinetic energy is proportional to temperature
no attractive forces
negligible particle volume
constant random motion
perfectly elastic collision

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9
Q

What does it mean when kinetic energy is proportional to temperature?

A

if temp is doubled, KE is doubled

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10
Q

What do no attractive forces work well for?

A

works well for low pressure and high temperature

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11
Q

What does it mean when there is constant random motion?

A

motion/direction of molecules and their speed

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12
Q

What does it mean when there are perfectly elastic collisions?

A

energy is transferred, no KE is lost

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13
Q

When will molecules have the same KE?

A

when in thermal equilibrium

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14
Q

What happens if the molecular mass is different?

A

there is same average amount of KE

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15
Q

How is it possible to have the same average KE when molecular mass is different?

A

they have different speeds
the larger the mass, the slower to speed of the particle

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16
Q

What is the ideal gas law?

A

based on KMT and assumes gases behave ideally
molecules have no volume (point particles)
no interaction between particles

17
Q

What does it mean when there is no interaction between particles?

A

particles will not repel particles next to each other

18
Q

What are the parameters affecting behavior of gases?

A

pressure (P)
volume (V)
temperature (T)
number of moles (n)

19
Q

What does P equal?

A

force/area

20
Q

What are the two kinds of pressure?

A

external and internal(relative) pressure

21
Q

What total pressure equal to?

A

Pexternal - Pinternal

22
Q

What is total pressure measured with?

A

a barometer

23
Q

What does a barometer do?

A

measures atmospheric pressure

24
Q

How does a barometer work?

A

height of Hg column on balances of forces: gravity pulls Hg down, atmospheric pressure pushed Hg up into evacuated tube

25
Q

What are the units of pressure?

A

1 atm = 760mmHg

26
Q

What is the avg pressure at sea level?

A

1 atm and is capable of supporting a column of Hg 760mm high

27
Q

What did Robert Boyle do?

A

worked to describe relationship between volume and pressure of a gas

28
Q

What is the Boyle equation?

A

P1V1=P2V2

29
Q

What does the Boyle equation assume?

A

temperature and number of moles remain constant

30
Q

What kind of relationship does volume and pressure have?

A

inverse