PL - Organic reactions *01 Flashcards

1
Q

acid hydrolysis of ester - products

A

splits the ester into a carboxylic acid and an alcohol

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2
Q

acid hydrolysis of an ester - conditions

A

reflux the ester with a dilute acid (hydrochloric or sulfuric)

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3
Q

base hydrolysis of ester - products

A

carboxylate salt and an alcohol

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4
Q

base hydrolysis of a ester - conditions

A

reflux with a dilute alkali (sodium hydroxide)

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5
Q

acyl chloride functional group

A

-COCl

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6
Q

acyl chloride - general formula

A

CnH2n-1OCl

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7
Q

acyl chloride - reaction with alcohols

A

vigorous reaction at room temp.

produce an ester and HCl

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8
Q

acyl chloride - reaction with amines

A

violent reaction at room temp.

produce an secondary amide and HCl

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9
Q

acid hydrolysis of an amide

A

heat with dilute acid (HCl) —> carboxylic acid + ammonium salt (NH4Cl)

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10
Q

base hydrolysis of an amide

A

heat with dilute alkali (NaOH) —-> carboxylate ion + ammonia gas (NH3)

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