Physical chemistry Flashcards

1
Q

define enthalpy change

A

the heat energy transferred in a reaction at standard conditions (constant pressure)

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2
Q

what is the standard pressure condition ?

A

100kPa (about 1 atm)

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3
Q

what is the standard temp condition ?

A

298K

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4
Q

name an exothermic reaction

A

combustion

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5
Q

name an endothermic reaction

A

thermal decomposition

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6
Q

what is the symbol for activation energy ?

A

Ea

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7
Q

what is standard enthalpy change of reaction ?

A

E.C. when reaction occurs in molar quantities shown in the chemical equation, under S.C.

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8
Q

what is standard enthalpy change of formation ?

A

E.C. when 1 mole of a compound is formed from its elements in their standard states, under S.C.

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9
Q

what is standard enthalpy change of combustion ?

A

E.C. when one mole of a substance is completely burned in oxygen, under S.C.

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10
Q

what is standard enthalpy change of neutralisation ?

A

E.C. when an acid and an alkali react together, under S.C., to form 1 mole of water

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11
Q

to break bonds, energy is …

A

needed

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12
Q

to make bonds, energy is …

A

released

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13
Q

describe the bonds in endothermic

A

bonds are broken

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14
Q

describe the bonds in exothermic

A

bonds are formed

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15
Q

what is bond dissociation enthalpy ?

A

amount of energy needed to break bonds per mole

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16
Q

what to remember with enthalpy change reactions

A

the sign (+ or -)

17
Q

what is Hess’s law ?

A

total enthalpy change is always the same, no matter which route is taken

18
Q

what is the standard change of formation of any element ?

A

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