PH and indicators Flashcards
Define PH
Ph = -log10[H+]
or
Ph= -log10[ H3+O]
What is the ph scale
a scale that runs from 0 to 14 that indicted its level of acidity or alkalinity
Give three limitations of the pH scale
The pH is inly useful/valid in the 0-14 range
The pH scale only applies to aqueous solutions
The pH scale does not work with very concentrated solutions
Arrhenious definition for an acid
dissociates in water to produce H+ or H3O+ ions
Arrhenious definition for a stong base
dissociated fully in water to produce H+/ H3O+ ions
Arrhenious definition for a weak base
dissociates only slightly in water to produce H+/H3o+ ions
Arrhenious definition for monobasic acid
each molecule dissociated to produce one H+ ions in solution
Arrhenious definition for dibasic acid
each molecule dissociates to produce one H+ ion in solution
Arrhenious definition for tribasic acid
each molecule dissociated to produce three H+ ions in solution
Arrhenious definition for a base
dissociated fully in water to produce OH- ions
Arrhenious definition for strong base
dissociated only slightly in water to produce OH- ions
Arrhenious definition for weak base
dissociates only slightly in water to produce OH-
Arrhenious definition for monobasic base
each molecule dissociated to produce one OH- ion in solution
Arrhenious definition for a dibasic base
each molecule dissociated to produce two OH- ions in solution
Arrhenious definition for tribasic base
each molecule dissociated to produce three OH- ions in solution
Two substances with the same pH
have the same [H+]
Have the same pOH
Have the same [OH-]
do acids still have an [OH-]?
yes they do… just very low - if asked for the [OH-] of an acid, treat ‘as if’ it is a base
Do Bases still have H+?
yes they do…just very low - if asked for the [H+] of an acid, treat it ‘as if’ it is an acid
what are acid base inicators
substances which change colour according to the ph of the solution in which they are placed
name a acid base indicator which change colour at 3-5 , 5-8 , 8-10
Methyl orange 3-5 yellow(base) to red(acid)
Litmus 5-8 Blue(base)to red(acid)
Phenolphthalein 8-10 Pink(base) to colourless (Acid)
what is the ph of an indicator
indicators themselves are weak acids or weak bases and dissociate in solution
HIn is an indicator that is itself a weak acid,Write a balanced equation to represent the dissociation of HIn in water/solution
Hln + H2O ⇌ ln- + H3O+
HIn is an indicator that is itself a weak acid
Place the indicator in an acid
concentration of H3O+ increases
the equilibrium shiftfs to decrease concentration of H3O+ to the left to use it up
Reverse reaction favoured
colour A (left hand side) due to increased concentration of Hln
HIn is an indicator that is itself a weak acid.
Place the indicator in a base
concentration of OH- increases, they will react with the H3O- ions to form H2O
concentration of H3O+ decreases
equilibrium shiftfd to increase concentration of H3O to produce more of it.
Foward reaction favoured to the right.
Colour B forms (RHS) to increase the concetration of ln-
XOH is an indicator that is itself a weak base.
Write a balanced equation to represent the dissociation of XOH in water / solution
XOH ⇌ X+ + OH-
XOH is an indicator that is itself a weak base.
Place the indicator in an acid
Concentration of H+ increases - they will react with OH- ions to from H2O. Concentration of OH- decreases.
Equilibrium shifts to increase concentration of OH- to produce more of it
Foward reaction favored to the right
Colour B forms due to increased concentration of OH- (RHS)
Place the indicator in an acid