Part 7 Flashcards

1
Q

what is the difference between ionic equation and net ionic equation?

A

net ionic does not include spectator ions, wheres ionic equation does!

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2
Q

whats the difference between a molecular equation and ionic equation?

A

ionic equation is composed of ions in solution ; molecular formula includes bonded molecules/compounds

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3
Q

neutralization rxn are a type of what?

A

double displacement rxn

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4
Q

when balancing equations who should be saved for last?

A

oxygen and hydrogen (usually the most represented in rxn)

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5
Q

what is true about rate law if you are provided with the RATE-DETERMINING step?

A

the exponents are equal to the coefficients (onlyyy of the rate-determining step!) not entire rxn!

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6
Q

if delta G is negative then the rxn is what?

A

spontaneous

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7
Q

if delta G is positive then the rxn is what?

A

not spontaneous

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8
Q

what does it mean if delta G is zero?

A

rxn is at equilibrium & thus,

delta H= (T)(delta S)

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9
Q

water boiling is an endo/exo- thermic rxn?

A

endothermic… bonds are being broken, energy is absorbed, and delta H is positive

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10
Q

under what conditions do gases deviate from ideal conditions?

A

low pressure, high temp

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11
Q

under what conditions are gases most soluble?

A

high pressure, low temp

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12
Q

what formula is used to calculate heat absorbed or released in rxn?

A

q= MCAT

heat= massspecific heatdelta T

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13
Q

what is a state function?

A

a property that does not depend on mechanism of change.. just before and after

(enthalpy, entropy, free energy)

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14
Q

if you increase the concentration of reactants, what happens to rxn rate?

A

it increases

all but zero order rxns

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15
Q

what happens to rxn rate if you increase temp?

A

rxn rate increase

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16
Q

true or false: transition states (top of potential energy diagram) has greater energy than either the reactants or products.

A

true … TS is where old bonds are weakened and new bonds are preparing/beginning to form

17
Q

on a potential energy diagram, if the products are LOWER than the reactants the rxn is what?

A

exothermic (-delta H)

18
Q

on a potential energy diagram, if the products are HIGHER than the reactants then the rxn is what?

A

endothermic (+ delta H)

19
Q

what is the second law of thermodynamics?

A

all spontaneous reactions result in an increase in entropy

20
Q

what is the gibbs free energy equation?

A

AG = AH - TAS