organic synthesis flow chart Flashcards
(30 cards)
1
Q
alkane to HA
A
- halogen
- UV
2
Q
HA to alcohol
A
- NaOH
3
Q
OH to HA
A
- sodium halide
- H2SO4
4
Q
HA to nitrile
A
- CN-
- ethanol
5
Q
HA to amine
A
- NH3
- ethanol
6
Q
alkene to HA
A
- hydrogen halide
7
Q
Alkene to Alkane
A
- H2
- Ni catalyst
8
Q
OH to alkene
A
- H3PO4 or H2SO4
- heat
9
Q
alkene to OH
A
- H2O (steam)
- H3PO4
10
Q
Nitrile to Amine
A
- H2
- Ni
11
Q
S - OH to ketone
A
- K2Cr2O7 / H2SO4
- reflux
12
Q
ketone to S-OH
A
- NaBH4
13
Q
P-OH to ALD
A
- K2CR2O7 / H2SO4
- distillation
14
Q
ALD to P-OH
A
- NaBH4
15
Q
ALD to CA
A
- K2Cr2O7 / H2SO4
- reflux
16
Q
CA to acyl chloride
A
- SOCL2
17
Q
Acyl chloride to CA
A
- H2O
18
Q
Acyl chloride to Ester
A
- alcohol
19
Q
Ester to carboxylate
A
- OH-
- heat
20
Q
OH to ester
A
- CA
- conc H2SO4 OR acid anhydride
21
Q
P-OH to CA
A
- K2Cr2O7 / H2SO4
- reflux
22
Q
acyl chloride to P-amide
A
- NH3
23
Q
acyl chloride to S-amide
A
- primary amine
24
Q
nitrile to CA
A
- H20 + HCl
- heat
25
hydroxy nitrile to CA
- H20/HCl
| - heat
26
hydroxy nitrile to amine
- H2 / Ni
27
ketone to hydroxy nitrile
- NaCN / H+
28
ester to CA
- dilute acid
| - heat
29
CA to ester
- alcohol
| - conc H2SO4
30
ALD to hydroxynitrile
- NaCN
| - H+
