Organic Chemistry Supplements Flashcards

1
Q

Reactions that alkanes undergo

A

Halogenation and Combustion

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2
Q

Reactions that alkenes undergo

A
Hydrogenation
Halogenation
Addition of hydrogen halides
Addition of water 
Hydroxylation
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3
Q

Reactions that alkynes undergo

A
Hydrogenation
Halogenation
Addition of hydrogen halides
Addition of water
Formation of metal acetylide
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4
Q

Reactions that alcohols undergo

A
Dehydration
Ester formation
Oxidation
Addition of Hydrogen Halides
Reaction with active metals
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5
Q

Obtained from destructive distillation of wood

A

Methanol

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6
Q

Methanol is converted to this, which is a starting material for plastics

A

Formaldehyde

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7
Q

Methanol is a denaturant in _______ which then makes it unfit for drinking due to its poisonous properties

A

Ethyl Alcohol

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8
Q

Also known as grain alcohol

A

Ethanol

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9
Q

Obtained from fermentation of sugar and starch

A

Ethanol

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10
Q

Rubbing alcohol

A

Isopropyl alcohol

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11
Q

Alcohol which is an intermediate in acetone production

A

Isopropyl alcohol

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12
Q

Main ingredient of suppositories

A

Glycerol

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13
Q

Anti-freeze agent for automobilies

A

Ethylene glycol

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14
Q

Starting material in the manufacturing of aspirin, detergents, dyes, herbicides, explosives etc.

A

Phenol

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15
Q

Other name of phenol

A

Carbolic acid

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16
Q

Saponated cresol

A

Lysol

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17
Q

Alcohol obtained from oil of peppermint

A

Menthol

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18
Q

Alcohol obtained from rose oil

A

Geraniol

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19
Q

Classification of ethers

A
  1. ) Open chains

2. ) Cyclic

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20
Q

Other names of epoxide

A

Oxacyclopropane

Oxirane

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21
Q

Ether used before as general anesthetic as it is safe in long surgical procedure

A

Ethyl ether

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22
Q

Adverse drug reaction of ethyl ether

A

Nausea and vomiting

Mucous membrane Irritation

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23
Q

Use of ethylene oxide

A

Fumigate textiles and grains

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24
Q

Use of monobenzone

A

Depigmenting agent

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25
Q

Eugenol is obtained from what oil

A

Clove oil

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26
Q

This is mixed with Zinc oxide cement to serve as temporary fillings

A

Eugenol

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27
Q

Reaction of Aldehydes and ketones with 2,4 DNPH

A

Formation of yellow hydrazones

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28
Q

Tollen’s test contains what reagent

A

Ammoniacal silver nitrate

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29
Q

Tollen’s test is a test for

A

Aliphatic and aromatic aldehydes

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30
Q

Benedict’s test results for aliphatic aldehydes and ketones would be positive (T/F)

A

True. Benedict’s test is a test for aliphatic aldehydes and also for ketones

31
Q

Iodoform test is a test for?

A

Methyl ketones

32
Q

Addition of alcohols to aldehydes or ketones results in

A

Acetal Formation

33
Q

Grignard reaction for aldehydes/ketones results in

A

Reduction to alcohol

34
Q

Use of formaldehyde

A

Specimen preservative (harden skin)

35
Q

Embalming fluid

A

Formalin

36
Q

Acetaldehyde is an intermediate in the manufacture of

A

Acetic acid
Ethyl Acetate
Vinyl Acetate (used for production of synthetic rubber and water based paint)

37
Q

Use of chloral

A

Starting material for DDT (insecticide)

38
Q

Constituent of the aroma of fresh bread

A

Butanal

39
Q

Oil of bitter almonds

A

Benzaldehyde

40
Q

Chief constituent of oil of cinnamon bark

A

Cinnamaldehyde

41
Q

Fragrant component of vanilla beans which is used as flavoring agent

A

Vanillin

42
Q

Acetone is used as

A

Solvent for paint lacquers and cellulose acetate

43
Q

Major constituent of male sex hormone and involved in the development of secondary sex characteristics

A

Testosterone

44
Q

Odorous component of musk which is a sex attractant

A

Muscone

45
Q

Muscone is use in cosmetics as

A

Fixative for perfumes

46
Q

Major component of lemon grass grass oil

A

Citral

47
Q

Methyl Ethyl Ketone is used as

A

solvent of lacquers and paints and plastics

48
Q

Acetophenone is used previously as

A

Hypnotic

49
Q

Chlorocetophenone is used as

A

Lacrimator in tear gas

50
Q

Keratolytic acid

A

Salicylic acid

51
Q

Salicylic acid is used in the treatment of

A

Fungal infections; removal of warts and corns

52
Q

Acid found in sour milk

A

Lactic acid

53
Q

Responsible for spoiling, fermentation of milk sugar, lactose

A

Lactic acid

54
Q

Acid found in several fruits especially grapes

A

Tartaric acid

55
Q

Pharmaceutical use of benzoic acid

A

Antifungal agent

56
Q

Sodium benzoate is used as

A

Food preservative

57
Q

Acetylsalicylic acid use

A

Analgesic, antipyretic, treatment of colds, HA, minor aches and pains

58
Q

Pharmaceutical use of p-aminobenzoic acid

A

Used in sun lotion to prevent UV from reaching skin

59
Q

Formed from reaction of carboxylic acid and alcohol

A

Esters

60
Q

Esters of glycerol and HMW fatty acids

A

Lipids

61
Q

Reaction of lipids with a strong inorganic base

A

Saponification

62
Q

Formed from hydrolysis of carboxylic acid

A

Anhydride

63
Q

Formed from condensation reaction of carboxylic acid and amine

A

Amide

64
Q

Acetanilide is used as

A

Antipyretic and analgesic

65
Q

Amide of niacin

A

Niacinamide

66
Q

Nicotinamide is used in the prevention of

A

Pellagra

67
Q

Sulfanilamide is employed in the treament of

A

Pneumonia, Diarrhea, Streptococcal infections

68
Q

ADR or sulfanilamide

A

Nausea, Dizziness, Anemia

69
Q

Cyclic compounds with N atom in the ring

A

Heterocyclic amines

70
Q

Aniline is used in

A

Preparation of dyes and drugs

71
Q

Amphetamine is what kind of drug

A

Psychomimetic

72
Q

Parent compound of barbiturates

A

Barbituric acid

73
Q

Use of saccharin

A

Sweetener