Nomenclature, Structural Isomerism & Alkanes Flashcards

1
Q

what is organic chemistry?

A

the study of compounds containing carbon and hydrogen and often many other elements e.g oxygen, nitrogen, chlorine

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2
Q

why can carbon form more compounds that every other element of the periodic table combined?

A

as it can covalently bond to itself to form chains and rings ( catenation)
it bonds with many other elements O,N,CL etc

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3
Q

what is a homologous series?

A

families of compounds with:

  • same general formula
  • molecular formulae of successive numbers differ by CH2.
  • they also have same functional group
  • similar chemical rectivity
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4
Q

what is a functional group?

A

atom or group of atom that gives characteristic chemical reactivity to a compound

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5
Q

how does the molecule change when increasing size?

A

the formula increases by 1 carbon and 2 hydrogens with each step

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6
Q

alkanes are the…

A

simplest one of the homologous series

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7
Q

what is the alkanes general formula?

A

CnH2n+2

so if there were 10 carbon atoms it would be c10h22

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8
Q

what type of hydrocarbons are alkanes?

A

saturated hydrocarbons

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9
Q

what does saturated hydrocarbons mean?

A

compounds that contain the elements hydrogen and carbon where the carbon is a single bond

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10
Q

what do alkanes only contain?

A

hydrogen and carbons

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11
Q

what is a substituent?

A

an atom or group of atom that branches out from the longest continuos carbon chain

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12
Q

what is the substituent for alkanes?

A

hydrocarbon chains (CH)

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13
Q

why are alkanes not very reactive?

A
  • contain non-polar bonds

- no region of high electron density (small amounts if alkanes do undergo combustion)

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14
Q

what is structural isomerism?

A

compounds with the same molecular formula (long version) but they have the different structural formula

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15
Q

what is homolytic radical substitution?

A

Reactions where bond-breaking involves each atom in the bond getting one of the
bonding electrons to form species with an unpaired electron where one atom (or
group of atoms) is swapped for another.

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16
Q

What does homolytic fission mean

A

Bond breaking where each species gets one binding electron

17
Q

What does radical mean (for homolytic radical substitution)

A

Species with an unpaired electrons

18
Q

Define substitution ( for homolytic radical substitution )

A

Swapping one atom or group of atoms for another atom