module 7 Flashcards

1
Q

R stereoisomer direction

A

clockwise

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2
Q

S stereoisomer direction

A

Counterclockwise

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3
Q
A

Isopropyl

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4
Q
A

t-butyl

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5
Q
A

sec-butyl

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6
Q
A

isobutyl

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7
Q

Z – stereoisomer

A

If the priority groups are on the same side

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8
Q

E – stereoisomer

A

If the priority groups are on opposite sides

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9
Q

Enantiomers

A
  • May have one or more stereocenters
  • All stereocenters must be switched between two structures
  • Have all the same physical properties except optical rotation
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10
Q

Diastereomers

A
  • Must have a minimum of two stereocenters
  • Must have at least one stereocenter remain the same
  • Completely different physical properties
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11
Q

Both enantiomers and diastereomers can affect _______ of a compound

A

biological impact

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12
Q

Suffix for alkanes

A

-ane

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13
Q

Suffix for alkenes

A

-ene

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14
Q

Suffix for alkynes

A

-yne

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15
Q

Substituent suffix for alkanes

A

-yl

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16
Q

Substituent suffix for alkenes

A

-enyl

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17
Q

Substituent suffix for alkynes

A

-ynyl

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18
Q
A

anisole

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19
Q
A

aniline

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20
Q
A

phenol

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21
Q
A

styrene

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22
Q
A

toluene

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23
Q
A

cumene

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24
Q

1-3

A

meta

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25
Q

1-4

A

para

26
Q

1-2

A

ortho

27
Q
A

steroid

28
Q
A

quinine

29
Q
A

morphine

30
Q
A

benzomorphan

31
Q
A

phenylpiperidines

32
Q
A

Barbituate

33
Q
A

benzodiazepine

34
Q
A

anesthetics

35
Q
A

penicillin

36
Q

What is the difference between a benzene and a heterocycle?

A

Benzene - aromatic
Heterocycle - not aromatic

37
Q
A

benzene

38
Q
A

pyrrole

39
Q
A

furan

40
Q
A

thiophene

41
Q
A

indole

42
Q
A

catechol

43
Q
A

pyrimidine

44
Q
A

pyridine

45
Q
A

imidazole

46
Q
A

Fullerene aka “Bucky Ball”

47
Q
A

naphthalene

48
Q
A

anthracene

49
Q
A

phenanthrene

50
Q
A

pyrene

51
Q
A

4-isopropylphenol (p-isopropylphenol)

52
Q
A

3-methoxyaniline (m-methoxyaniline)

53
Q
A

2-bromotoluene (o-bromotoluene)

54
Q
A

3-methylstyrene (m-methylstyrene)

55
Q
A

morpholine

56
Q
A

piperazine

57
Q
A

piperidine

58
Q
A

tetrahydropyran

59
Q
A

tetrahydrofuran

60
Q
A

pyrrolidine