module 7 Flashcards by Michael Sokol

Q

R stereoisomer direction

A

clockwise

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Q

S stereoisomer direction

A

Counterclockwise

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Q

A

Isopropyl

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Q

A

t-butyl

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Q

A

sec-butyl

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Q

A

isobutyl

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Q

Z – stereoisomer

A

If the priority groups are on the same side

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Q

E – stereoisomer

A

If the priority groups are on opposite sides

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Q

Enantiomers

A

May have one or more stereocenters
All stereocenters must be switched between two structures
Have all the same physical properties except optical rotation

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Q

Diastereomers

A

Must have a minimum of two stereocenters
Must have at least one stereocenter remain the same
Completely different physical properties

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Q

Both enantiomers and diastereomers can affect _______ of a compound

A

biological impact

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Q

Suffix for alkanes

A

-ane

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Q

Suffix for alkenes

A

-ene

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Q

Suffix for alkynes

A

-yne

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Q

Substituent suffix for alkanes

A

-yl

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Q

Substituent suffix for alkenes

A

-enyl

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Q

Substituent suffix for alkynes

A

-ynyl

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Q

A

anisole

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Q

A

aniline

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Q

A

phenol

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Q

A

styrene

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Q

A

toluene

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Q

A

cumene

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Q

1-3

A

meta

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Q

1-4

A

para

Q

1-2

A

ortho

Q

A

steroid

Q

A

quinine

Q

A

morphine

Q

A

benzomorphan

Q

A

phenylpiperidines

Q

A

Barbituate

Q

A

benzodiazepine

Q

A

anesthetics

Q

A

penicillin

Q

What is the difference between a benzene and a heterocycle?

A

Benzene - aromatic
Heterocycle - not aromatic

Q

A

benzene

Q

A

pyrrole

Q

A

furan

Q

A

thiophene

Q

A

indole

Q

A

catechol

Q

A

pyrimidine

Q

A

pyridine

Q

A

imidazole

Q

A

Fullerene aka “Bucky Ball”

Q

A

naphthalene

Q

A

anthracene

Q

A

phenanthrene

Q

A

pyrene

Q

A

4-isopropylphenol (p-isopropylphenol)

Q

A

3-methoxyaniline (m-methoxyaniline)

Q

A

2-bromotoluene (o-bromotoluene)

Q

A

3-methylstyrene (m-methylstyrene)

Q

A

morpholine

Q

A

piperazine

Q

A

piperidine

Q

A

tetrahydropyran

Q

A

tetrahydrofuran

Q

A

pyrrolidine