module 2: 6.2 electronegativity and polarity Flashcards

2.2.2 electronegativity and polarity

1
Q

define the term electronegativity

A

the ability of an atom to attract the bonding electrons in a covalent bond

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2
Q

what is the most electronegative element

A

F, Flourine

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3
Q

how does electronegativity change across the periodic table

A
across the periodic table:
- the nuclear charge increases
- the atomic radius decreases
thus the electronegativity increases
going up the periodic table electronegativity increases
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4
Q

what electronegativity difference is required for a bond type to be covalent

A

0

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5
Q

what electronegativity difference is required for a bond type to be polar covalent

A

0 to 1.8

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6
Q

what electronegativity difference is required for a bond type to be ionic

A

greater than 1.8

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7
Q

how is the bond shared in a non-polar bond

A

the bonded electron pair is shared equally between the bonded atoms.
this is due to the bonded atoms having the same or similar electronegativity.
E.g. H2 or Cl2

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8
Q

how is the bond shared in a polar bond

A

the bonded electron pair is shared unequally between the bonded atoms. A bond will be polar when the bonded atoms are different and have different electronegativity values, resulting in a polar covalent bond.
E.g. HCl
the H–Cl bond is polarised with a small partial positive charge on the hydrogen and a small negative charge on the chlorine atoms. This causes the molecule to be polar.
It is a permanent dipole

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9
Q

define the term dipole

A

a dipole is the separation of opposite charges

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