module 2: 6.2 electronegativity and polarity Flashcards
2.2.2 electronegativity and polarity
define the term electronegativity
the ability of an atom to attract the bonding electrons in a covalent bond
what is the most electronegative element
F, Flourine
how does electronegativity change across the periodic table
across the periodic table: - the nuclear charge increases - the atomic radius decreases thus the electronegativity increases going up the periodic table electronegativity increases
what electronegativity difference is required for a bond type to be covalent
0
what electronegativity difference is required for a bond type to be polar covalent
0 to 1.8
what electronegativity difference is required for a bond type to be ionic
greater than 1.8
how is the bond shared in a non-polar bond
the bonded electron pair is shared equally between the bonded atoms.
this is due to the bonded atoms having the same or similar electronegativity.
E.g. H2 or Cl2
how is the bond shared in a polar bond
the bonded electron pair is shared unequally between the bonded atoms. A bond will be polar when the bonded atoms are different and have different electronegativity values, resulting in a polar covalent bond.
E.g. HCl
the H–Cl bond is polarised with a small partial positive charge on the hydrogen and a small negative charge on the chlorine atoms. This causes the molecule to be polar.
It is a permanent dipole
define the term dipole
a dipole is the separation of opposite charges