MIDTERM 02 - Structural Effects on Acidity and Basicity Flashcards

1
Q

Substance that increases the concentration of H+ ions

A

Arrhenius acid

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2
Q

Substance that increases the concentration of OH- ions

A

Arrhenius base

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3
Q

Is a substance that donates a proton to another substance

A

Bronsted-Lowry acid

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4
Q

Is a substance that accepts a proton

A

Bronsted-Lowry base

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5
Q

Formed by removing a proton from the acid

A

Conjugate base

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6
Q

Formed by adding a proton to the base

A

Conjugate acid

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7
Q

A substance capable of acting as either an acid or a base

A

Amphiprotic

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8
Q

Is a measure of the tendency of a compound to lose a proton

A

Acidity

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9
Q

Is a measure of a compound’s affinity for a proton

A

Basicity

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10
Q

Ka; the higher the Ka, the stronger the acid

A

Acid-dissociation constant

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11
Q

Kb; the higher the Kb, the stronger the base

A

Base-dissociation constant

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12
Q

Is a substance that accepts an electron pair

A

Lewis acid

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13
Q

Is a substance that donates an electron pair

A

Lewis base

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14
Q

Other name for Lewis acids

A

Electrophiles

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15
Q

Other name for Lewis bases

A

Nucleophiles

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16
Q

Are organic compounds that contain a hydrogen atom bonded to an electronegative oxygen

A

Organic acids

17
Q

Shift in electron density through charge polarization transmitted through sigma bonds

A

Inductive effect

18
Q

Stabilizes conjugate base

A

Electron-withdrawing groups

19
Q

Destabilizes conjugate base

A

Electron-donating groups

20
Q

Results from the presence of bulky groups and results to congestion and twisting of bonds

A

Steric effect