FINAL 03 - Reaction Mechanisms Quiz Flashcards

1
Q

Typical reaction of alkynes

A

Electrophilic addition

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2
Q

Correct symbol for nucleophile

A

Nu- or Nu:

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3
Q

The typical electrophilic addition to alkenes is __________

A

Bimolecular with 2 steps

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4
Q

Does not occur in syn stereochemistry

A

Halogenation of alkenes

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5
Q

Mineral chameleon is a stronger oxidizing agent in __________

A

Acidic medium

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6
Q

Bromine test with phenol would cause __________

A

Disappearance of brown color, change in litmus from blue to red

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7
Q

Adam’s catalyst

A

PtO2

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8
Q

Oxidation of alkenes without hydrogen substituents on the C on the double bonds with acidic KMnO4 yields __________

A

2 ketones

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9
Q

Does not occur in the laboratory

A

Aromatic hydroxylation

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10
Q

Reaction of alkyl halides with a sodium acetate in aqueous acetic acid occurs via __________

A

SN1

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11
Q

What is true about HS- and OH-?

A

OH- is a stronger base and weaker nucleophile

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12
Q

What is true about SN1 and SN2?

A

SN2 more easily occurs with primary alkyl groups

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13
Q

Which is true about SN1?

A

Inversion and retention occurs

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14
Q

Compounds that are positive for Baeyer’s

A

Aliphatic alkene and alkyne

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15
Q

Product of reaction of 2-methylpropene with HCl

A

2-chloro-2-methylpropane

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