Memorise Flashcards
What are the reaction conditions for nuclear fusion?
High temperature and pressure
What is formed when group 2 reacts with water?
Metal hydroxide and hydrogen
What is the trend in reactivity if group 2 with hydroxides?
Increase in reactivity
What is formed when group 2 reacts with oxygen?
Metal oxide
What is the trend in thermal stability of carbonates?
Increases down the group
What is formed when group 2 carbonates decompose?
Carbon dioxide and metal oxide
What is the trend in solubility of group 2 hydroxides?
Increase in solubility
That is the trend in solubility of group 2 carbonates?
Decreases down the group
Test for transition metals?
Sodium hydroxide
Test for carbonates?
HCl
Test for sulfates?
Barium chloride
Test for ammonia?
Red litmus paper turns blue
Test for halides?
Silver nitrate
ReCtion conditions of hydrogenation?
Nickel catalyst with heat and pressure
Platinum catalyst at room temperature
What are the reaction conditions for hydration of alkemes?
Concentrated h2so4
Steam
Heat and pressure
Appearance of the halogens at room temp?
Fluorine- pale yellow ga
Chlorine- yellow/green gas
Bromine - red/brown liquid
Iodine - shiny grey solid
What is the trend in reactivity if halogens?
Decreases in reactivity down the group
Colours of halogens in water?
Chlorine - colourless
Bromine- yellow/ orange
Iodine - brown
Colours of halogens in hexane?
Chlorine- colourless
Bromine - orange/ red
Iodine- violet
How to produce HBr and HI?
Phosphoric avid
HBr and sulfuric acid?
SO2
HI with sulfuric acid?
H2S
What is the trend in thermal stability of hydrogen halides?
Decreases
Hydrogen halides with ammonia?
Ammonium halide
Acidity of hydrogen halides?
All strong acids except fluorine as it doesn’t dissociate
What is the trend in booking points of haloalkanes?
Increases down the group
Nucleophillic substitution with water or hydroxides?
Alcohol
Nucleophillic substitution with ammonia?
Amines
What is the course of the trend in reactivity if haloalkanes?
Bond enthalpy
What is the trend in reactivity if haloalkanes?
Increase in reactivity
Phenols and alkali?
React to form salt and water
Phenol and carbonate?
No reaction
Carboxylic acid and carbonate?
ReCtion - fizzing
Phenol and acid anhydride?
Ester and a carboxylic acid
Test for phenol!
Iron iii chloride
Purple
Formation of eaters from acohol?
Carboxylic acid with concentrated sulfuric or hydrochloride acid
Primary alcohol distilled with acidified potassium dichromate?
Aldehyde
Reflux of primary alcohol?
Carboxylic acid
Oxidation of secondary alcohol?
Ketone
Oxidation of tertiary alcohol?
Nothing
How to dehydrate alcohols?
Heated aluminate or reflux with concentrated sulfuric acid to make an Allene
what is the gradient in the arhennius equation?
-Ea/R
what is the test for nitrate v?
warm with devardas alloy and NaOH
produces ammonia gas test with damp red litmus paper = blue
what is the test for ammonium?
warm with NaOH
produces ammonia gas
damp red litmus paper blue
what do you spray a chromatogram with?
ninhydrin solution
reaction conditions to hydrolyse a protein?
hot aqeuous 6 molar HCl
what is a pharmacophore?
drug that fits into the receptor site making it medicinally active
why might a pharmocaphore not work?
not the right shape/size
dp-dp, hydrogen, ionic, IDID
orientation
carboxylic acid +metal
metal ethanoate - carboxylate and hydrogen
carboxylic acid + carbonate
carboxylate + water + CO2
carboxylic acid +alkali
salt and water
what are the conditions for hydrolysis of esters?
reflux with either moderately concentrated HCl or NaOH
conditions for hydrolysis of amides?
reflux with moderately concentrated HCl(4M) or NaOH (2M)
what is an acyl chloride?
COCl group
what are optical isomers called?
enantiomers
what are the two types of polymers?
addition and condensation
nylonx,y what is x and what is y?
x=carbons of the diamine
y=carbons on the dicarboxylic acid
how do enantiomers act differently?
rotate plain polarised light in opposite directions
form differen shapes so fit differently in active site
what is a bronsted lowrey base?
accepts h+
test for nitrate(v)
NaOH and devardas alloy and heat = ammonia gas
turns damp red litmus paper blue
test for Cl-?
nitric acid and silver nitrate forms white ppt
soluble in dilute ammonia
test for Br-?
nitric acid and silver nitrate forms cream ppt
soluble in concentrated ammonia and insoluble in dilute ammonia
test for I-?
Nitric acid and silver nitrate forms yellow ppt
insoluble in conc and dilute ammonia
test for sulphate (SO4)2-
Barium hydroxide forms white ppt
test for carbonate (CO3)2-
HNO3 = fizzing
test for hydroxide ions
pH paper
what forms when Cu2+ reacts with CO3 2-?
green/blue ppt
what forms when Fe2+ reavts with carbonate ions?
green ppt
what happens when Fe3+ reacts with carbonate ions?
brown ppt
what happens when Zn2+ reacts with carbonate ions
white ppt
what happens when Ca 2+ reacts with carbonate ions?
white ppt
what happens when barium ions react with carbonate ions?
white ppt
what happens when Pb2+ reacts with carbonate ions
white ppt
Hydroxide ions and alumninium ions?
white ppt dissolves in excess
hydroxide ions and Cu2+
blue ppt
hyrdoixde ions and Fe2+
dirty green ppt
hydroxide ions and Fe3+
orange/brown ppt
hydroxide ions and Zn2+
white ppt
hydroxide ions and Ca2+
white ppt
hydroxide ions and Ba2+
white ppt
hydroxide ions and Pb2+
white ppt
Ca2+ and SO4 2-
white ppt
Ba 2+ and SO4 2-
white ppt
Pb2+ and SO4 2-
white ppt
Ag+ and SO42-
white ppt
Pb2+ and I-
bright yellow ppt