Lecture 4 Flashcards

1
Q

what are chemical reactions

A

the breaking/forming of bonds

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2
Q

What is energetic coupling

A

when a spontaneous reaction drives a non-spontaneous reaction

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3
Q

What are enzymes

A

catalysts that increase the rate of a reaction

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4
Q

What are allosteric enzymes

A

enzymes that are activated/inhibited as when binding to another molecule changes its shape

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5
Q

What is free radical (reactive oxygen species)

A

it describes atoms/molecules that contain unpaired electrons that become unstable

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5
Q

What happens to bonds during reactions

A

bonds change how they are linked to each other

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6
Q

What is gibs free energy

A

delta G - the amount of energy in a system to do work

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7
Q

What happens if products have more energy than reactants

A

delta G is (+), its endergonic, and non-spontaneous

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8
Q

What happens when reactants have more energy than products

A

delta G is (-), its exergonic, and spontaneous

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9
Q

What is enthalpy and the formula for it

A

energy available for work + energy lost
delta G= delta H - T delta S

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10
Q

In a catabolic reaction what is the enthalpy formula

A

(-) delta G= small delta H - big T delta S

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11
Q

In a anabolic reaction what is the enthalpy formula

A

(+) delta G= big delta H - small T delta S

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12
Q

in energy coupling, if reaction 1 is delta G = -7.3

A

spontaneous cause (-)

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13
Q

in energy coupling, if reaction 2 is delta G = 3.3

A

non-spontaneous cause (+)

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14
Q

in energy coupling, if result is delta G = -4.0

A

couples reaction due to (-)

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15
Q

What happens in Intermediate delta G

A

ATP drives the reaction and replenishes its self

16
Q

What is activation energy (Ea)

A

energy needed to start a reaction

17
Q

What happens if the amount of Ea is low

A

less energy is needed to start a reaction

18
Q

What is the connection between enzymes and Ea

A

they work by lowering Ea by forming a complex with substrate to get ES and then the substrate becomes a product and disassociates from the enzyme

19
Q

What are enzyme shapes like

A

They are like protein

20
Q

What is the Active site and how does it affect Ea

A

sites that bond with substrate and converts the substrate to products

lowers Ea

21
Q

What affects enzymes

A

activators/inhibitors

22
Q

What do activators do

A

increase enzyme activities

23
Q

What do inhibitors do

A

they decrease/block enzyme activities and can be reversable or not

24
Q

How do inhibitors work

A

They bind to active sites and compete with substrates

25
Q

What do allosteric enzymes do

A

They bind to enzymes to change its shape