KTG Flashcards

1
Q

Vcritical =

A

3b

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2
Q

Pcritical

A

a/27b^2

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3
Q

Tcritical

A

8a/27Rb

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4
Q

PV/RT

A

3/8

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5
Q

Mean free path

A

(1/root2 ) 1/npid^2

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6
Q

Relaxation time

A

(1/v) * 1/npid^2

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7
Q

No of degrees of freedom in a vibrational mode

A

2

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8
Q

PV^x = constant, C = ?

A

C = Cv + R/1-x

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9
Q

volume coeff at high temp

A

becomes constant

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10
Q

MP with inc in pressure

A

decreases(ice exp)

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11
Q

BP with inc in pressure

A

Inc

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12
Q

Newton’s law of cooling graph equation:

A

dQ/dt = -k(T2-T1)

ms dT/dt = -k(T2 -T1)

log(T2 - T1) = -kt

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13
Q

Adiabatic wall fixed vs movable

A

Fixed: A and B are independent of each other
Movable: Pa = Pb

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14
Q

Diathermic fixed vs movable

A

Fixed: Ta = Tb
Movable: Ta = Tb, Pa = Pb

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15
Q

Tyre bursting:

A

Irreversible adiabatic

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16
Q

Work done in adiabatic process

A
W = (P1V1 - P2V2)/ (gamma -1)
W = nR(T1 - T2)/(gamma - 1)
17
Q

Efficiency of fridge

A

Q2/W * 100

18
Q

Efficiency of engine

A

W/Q1 * 100

19
Q

Specific heat capacity of a solid

A

3R

C = delta Q/ delta T = deltaU/deltaT

20
Q

One calorie definition

A

Amt of heat required to heat solid from 14.5degC to 15.5degC

21
Q

delta U extensive or intensive

A

extensive

22
Q

Second law points

A

Efficiency of engine can never be 1

Efficiency of fridge can never be inf

23
Q

Kelvin Planck statement

A

Complete conversion of heat to work not possible

24
Q

Clausius statement

A

Heat can never flow from cold to hot body without any work

25
Q

Example of reversible process

A

Quasistatic isothermal expansion of ideal gas

26
Q

Carnot engine processes

A

Reversible, adiabatic