aldehydes Flashcards

1
Q

mesitylene

A

benzene ring with 3methyls at ortho para positions

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2
Q

RNH2 + carbonyl

A

Schiff’s base

substituted imine

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3
Q

Formalin composition

A

40% formaldehyde

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4
Q

Partial hydrolysis of cyanides

A

Amide

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5
Q

Hydrolysis of acyl chloride

A

Acid

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6
Q

Stability of alkenes

A

same grp same side > trans >cis

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7
Q

Heat of hydrogenation and stability

A

Inversely

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8
Q

Heat of combustion and branching

A

inversely

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9
Q

Heat of combustion and stability of alkene

A

Inversely

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10
Q

basicity order pyridine pyrolle aniline

A

pyridine>aniline>pyrolle

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11
Q

Keto enol tautomerism condition

A

Next to carbonyl there has to be an sp3 carbon that has at least one H atom

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12
Q

Keto more stable than enol. But exceptions

A

conjugation
aromaticity
intramolecular H bonding

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13
Q

non zero dipole moment example

A

quinol, 1,4benzene dicarboxylic acid

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14
Q

No of optical isomers

A

Unsymmetric: 2^n
Symmetric: 2^n-1 + 2^p-1

p = (n+1)/2 or n/2

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15
Q

Which product can undergo racemisation

A

The one that is chiral

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