aldehydes Flashcards
mesitylene
benzene ring with 3methyls at ortho para positions
RNH2 + carbonyl
Schiff’s base
substituted imine
Formalin composition
40% formaldehyde
Partial hydrolysis of cyanides
Amide
Hydrolysis of acyl chloride
Acid
Stability of alkenes
same grp same side > trans >cis
Heat of hydrogenation and stability
Inversely
Heat of combustion and branching
inversely
Heat of combustion and stability of alkene
Inversely
basicity order pyridine pyrolle aniline
pyridine>aniline>pyrolle
Keto enol tautomerism condition
Next to carbonyl there has to be an sp3 carbon that has at least one H atom
Keto more stable than enol. But exceptions
conjugation
aromaticity
intramolecular H bonding
non zero dipole moment example
quinol, 1,4benzene dicarboxylic acid
No of optical isomers
Unsymmetric: 2^n
Symmetric: 2^n-1 + 2^p-1
p = (n+1)/2 or n/2
Which product can undergo racemisation
The one that is chiral