Amines Flashcards
1
Q
Curtius rearrangement
A
NaN3 + RCONH2 ———-> RNH2 + CO2 + N2
2
Q
Schmidt reaction
A
HN3 + RCONH2 ———–> RNH2 + N2 + CO2
3
Q
Gabriel synthesis possible only for
A
1deg aliphatic amines
4
Q
Quaternary ammonia halide + moist Ag2O
A
The alkyl grp having a beta H will leave in such a way that sterric hinderance for resulting alkene is least
5
Q
Zwitter ion when to anode when to cathode
A
acidic medium cathode
basic medium anode
6
Q
coupling BDC with phenol vs coupling BDC with aniline
A
phenol: orange
aniline: yellow
(OH means orange)
