Alcohols ethers Flashcards
1
Q
Type of addition for oxy-demercuration
A
anti
2
Q
Type of addition for hydroboration oxidation
A
syn
3
Q
Na/C2H5OH
A
CEKA Cyanide to amine Ester to alcohol ketone to alcohol aldehyde to alcohol
4
Q
LiAlH4 triple bond reduction
A
trans double bond
5
Q
Clemenson exception
A
alpha or beta keto acids dont give clemenson
6
Q
NaHCO3 to give CO2 is shown by
A
only carboxylic acids
7
Q
Rxn with Na to give H2 is shown by
A
all alcohols and carboxylic acids
8
Q
Rxn with amide to give NH3 is shown by
A
all alcohols and carboxylic acids
9
Q
Rxn with base to give salt+water
A
methanol, phenol and carboxylic acids
10
Q
dehydrating agents
A
POCl3, P2O5, Al2O3,Pyridine,H2SO4
11
Q
OPR use
A
2deg —–> ketone
12
Q
fenton’s reagent(Fe2+ + H2O2)
A
benzene ——-(fentons)—–> phenol
13
Q
toluene ——-(fentons)——>
A
p-cresol
14
Q
phenol + benzoyl chloride
A
benzoylation happens(like acetylation)
15
Q
phenol + CCl4
A
salicylic acid
