Ionic Equilibrium Flashcards
pH due to addition of water
pH’= pH + Log n
pH of a solution containing weak acid or weak base
Calculate α=√ka/C
If α
pH for neutralisation of strong acid and strong base
Calculate mill implies of H+ from strong acid and millimoles of OH- from strong base. React H+ and OH - irreversibly to form water. If both the limiting agent then pH of sol =7
For OH- is limiting agent then
pH= - log ( millimoles of H+ remaining/ volume in mL)
Else pOH= -log ( millimoles of OH- remaining / volume in ml)
pH in salt hydrolysis
Calculate degree of hydrolysis h = √kW÷C.kA
If h
How to calculate degree of hydrolysis h of salt of weak acid and weak base ?
pH=7 + 1/2 ( pka -pkb)
h= √kh÷1+√kh
The eq of pH does not contain any conc hence as long as salt is same , ph remains same irrespective of conc.
How to calculate pH of amphiprotic salt ?
pH= pKa+pKa2/2
How to calculate pH of buffer sol of weak acid and its conjugate base
pH= pKa+ log [salt]/[acid]
Acidic buffer
How to calculate ph of buffer sol of weak base and its conjugate acid
pOH = pkb + log [salt]/[base] ( Basic buffer )
How to calculate pH of Na₂CO₃?
Calculate h=√kW÷C x ka2
If h