Ionic Equilibrium Flashcards

1
Q

pH due to addition of water

A

pH’= pH + Log n

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2
Q

pH of a solution containing weak acid or weak base

A

Calculate α=√ka/C

If α

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3
Q

pH for neutralisation of strong acid and strong base

A

Calculate mill implies of H+ from strong acid and millimoles of OH- from strong base. React H+ and OH - irreversibly to form water. If both the limiting agent then pH of sol =7
For OH- is limiting agent then
pH= - log ( millimoles of H+ remaining/ volume in mL)
Else pOH= -log ( millimoles of OH- remaining / volume in ml)

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4
Q

pH in salt hydrolysis

A

Calculate degree of hydrolysis h = √kW÷C.kA

If h

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5
Q

How to calculate degree of hydrolysis h of salt of weak acid and weak base ?

A

pH=7 + 1/2 ( pka -pkb)
h= √kh÷1+√kh
The eq of pH does not contain any conc hence as long as salt is same , ph remains same irrespective of conc.

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6
Q

How to calculate pH of amphiprotic salt ?

A

pH= pKa+pKa2/2

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7
Q

How to calculate pH of buffer sol of weak acid and its conjugate base

A

pH= pKa+ log [salt]/[acid]

Acidic buffer

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8
Q

How to calculate ph of buffer sol of weak base and its conjugate acid

A

pOH = pkb + log [salt]/[base] ( Basic buffer )

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9
Q

How to calculate pH of Na₂CO₃?

A

Calculate h=√kW÷C x ka2

If h

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