hybridisation Flashcards
what is hybridisation?
Creating orbitals that suit the bonding requirements in response to the electrostatic environment
what is an orbital?
a mathematical expression used to describe the portability of finding an electron in that area at any given time
What is required for atomic orbitals to overlap to form a molecular bond?
the two electrons within the atomic orbitals must have opposite spins
What are the chances of finding an electron by the nucleus if it sits in the p orbital?
there is no chance, therefore the p orbital has a nodal plane in the center ( it looks like an infinity. Electrons are too far away from the nucleus, so more likely to be found further away.
what is a head - on overlap?
this is sigma bond, formed when two orbitals are in the same phase overlap. this is a single bond.
why can you have free rotation around a single bond?
because the orbitals can retain the same amount of contact therefore single bond stays in place.
what is the hybridisation of 1 bonded group?
s
what is the hybridisation of 2 bonded group?
sp
what is the hybridisation of 3 bonded group?
sp2
what is the hybridisation of 4 bonded group?
sp3
what is the hybridisation of 5 bonded group?
sp3d