Halogen reactions Flashcards
what will Cl2 displace?
Br- and I-
what will Br2 displace?
I- only
what will I2 displace?
I2 will not displce any halide ions
observation for mixing aqueous Cl2 and aqueous KBr
orange solution formed with solvent
observation for mixing Cl2 and KI (both aqueous)
pink solution formed with solvent
observation for mixing Br2 and KI (both aqueous)
pink solution formed with solvent
testing for halides steps
-add dilute HNO3 to each test tube of unknown aqueous halide
-add aqueous silver nitrate (AgNO3)
F- gives no precipitate
Cl- gives white ppt
Br- gives cream ppt
I- gives yellow ppt
if adding silver nitrate gives ppts which are hard to distinguish, what further steps and observations should be taken?
- add dilute ammonia to each test tube
- Cl- ppt dissolves in dilute ammonia
- Br- ppt dissolves in conc. ammoina
- I- is insoluble in dilute and conc. ammonia, so no change.