H5 Flashcards

1
Q

what does pH stand for?

A

potential of hydrogen (it is the number of hydrogen ions)

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2
Q

what is the pH of sea water

A

between 8,1-8,2

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3
Q

how does the pH influence corals?

A

Corals are affected by the amount of dissolved co2: more dissolved co2 can ultimately reduce the calcium carbonate available for corals to make their calcareous skeleton.

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4
Q

which other organisms can pH influence? (4)

A
  1. coccolithophores
  2. foraminifera
  3. crustaceans
  4. other shellfish/animals (calcareous house builders)
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5
Q

what is water?

A

H2O, 2 hydrogen atoms and one oxygen atom chemically bound into one molecule

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6
Q

chemical properties of H and O atoms

A
  1. hydrogen has one proton in the nucleus, with one electron around it
  2. oxygen has eight protons in the nucleus, with eight electrons around it
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7
Q

solid form of water: atoms and molecules

A

ice. the molecules hardly move and stay on the same place

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8
Q

fluid form of water: atoms and molecules

A

water. the molecules move quickly and far from each other. movement is free compared to each other

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9
Q

gas form of water: atoms and molecules

A

water vapor. the molecules move very quickly and very far. they are full of energy. they are, in most part, independent

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10
Q

what type of structure is a water molecule?

A

dipole. it is asymmetric

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11
Q

is oxygen a negative or positive charge?

A

negative charge

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12
Q

is hydrogen a negative or positive charge?

A

positive

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13
Q

cluster forming of water molecules

A
  1. cumulative positive charge
  2. cumulative negative charge
  3. bound through hydrogen bonds
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14
Q

water has a high heat capacity

A
  1. a lot of energy is needed to heat 1 gram of water by 1 degree C
  2. how higher the temperature, how less H2O clusters there are
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15
Q

temp determines density:

A
  1. atoms and molecules move quicker

2. density (mass/volume) decreases; there is less mass (atoms) in the same volume

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16
Q

molecular structure of ice: density… how does ice float?

A
  1. water molecules in ice are structured hexagonally
  2. in the hexagon is an open space, whereby it is 8% less dense than water
  3. fluid water has a lot of hydrogen compounds (waterstofverbindingen), whereby it is denser than ice
  4. structured with covalent bonds.

ice is less dense than water, so it floats on the denser, fluid water

17
Q

dissolved substances in water (5)

A
  1. salt
  2. nutrients
  3. gasses
  4. trace elements
  5. organic compounds
18
Q

average salt in sea water

A

35g salt by 1,000g sea water.
= 35 parts per thousand (ppt)
35 promille (means ppt)
35 = 3,5% of seawater is salt

19
Q

salinity variation

A

through percipitation (neerslag) and evaporation (verdamping)

20
Q

salt content in sea water

A
  1. natrium and chloride cover together almost 86% dissolved salt in sea water
  2. little variation over time –> therefore, conservative property of seawater
21
Q

nutrient content in sea water

A
  1. small amount…measured in parts per million (ppm)

2. large variation over time –> therefore, nonconservative property of seawater

22
Q

gas content in sea water

A

nitrogen (stikstof) and noble gases are inert because they are chemically nonrecreative

23
Q

trace element content in sea water

A
  1. very small amounts. measured in ppm or even parts per billion (ppb)
  2. than to the small amount, trace elements can play a crucial role in life and death
24
Q

large complex molecules

A
  1. fat
  2. carbohydrates
  3. hormones
  4. proteins
  5. vitamins
25
Q

where does salt in sea water come from?

A
  1. erosion from land
  2. reaction of lava with sea water
  3. detached from stones through chemical reactions between stones and acid rain water
26
Q

how do we measure salinity?

A
  1. refractometer (%)
  2. multimeter (EGV)
  3. measure chlorine (total halogens in sea water - chlorine, bromine, iodine and fluorine. salinity = 1,8065 x chlorineity)
27
Q

thermocline

A

exists where warm water (lower density) is next to cold water (higher density). temp and density change very quickly with thermocline. pole areas don’t have a thermocline, but temperate areas have thermoclines in different seasons as it is temperature dependent

28
Q

halocline

A

abrupt difference in salinity between surface sea water and deeper water. dependent on salinity

29
Q

pychnocline

A

abrupt difference in density between surface sea water and deeper water. dependent on density

30
Q

layers in sea water

A

surface water is lighter than deep water because it has a lower salinity and higher temperature (and thus, lower density)

31
Q

gases in the surface layer

A

a lot of oxygen through photosynthesis and diffusion from the atmosphere

32
Q

gases in the pycnocline layer

A

little oxygen at 150-1500m through large quantities of organisms respirating

33
Q

gases in the the deep sea

A

relatively large quantity of oxygen through the sinking of oxygen-rich cold surface water to the bottom

34
Q

more H+ ions dissolved means…

A

the more acidic the sea water

35
Q

ore OH- ions disolved means…

A

the more alkaline the sea water

36
Q

three forms of dissolved CO2 in the sea:

A
  1. carbon dioxide (CO2)
  2. bicarbonate (HCO3-)
  3. carbonate (CO3ˆ2-)
37
Q

what is pH dependent on?

A

the amount of dissolved CO2 in sea water

38
Q

What happens when CO2 is dissolved in sea water?

A

It reacts to carbonic acid (koolzuur –> H2CO3) and then to bicarbonate and/or carbonate. Then the hydrogen ion comes free (H+)