Gases Flashcards

1
Q

Pressure

A

Force exerted per unit area

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2
Q

Pascal (Pa)

A

SI unit of pressure; 1 Pa = 1 N/m^2

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3
Q

Bar (b)

A

Unit of pressure; 1 bar = 100,000 Pa

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4
Q

Pounds per Square Inch (psi)

A

Unit of pressure common in the US

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5
Q

Atmosphere (atm)

A

Unit of pressure; 1 atm = 101,325 Pa

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6
Q

Barometer

A

device used to measure atmospheric pressure

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7
Q

Torr

A

Unit of pressure; 1 torr = 1/760 atm

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8
Q

Hydrostatic Pressure

A

Pressure exerted by a fluid due to gravity

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9
Q

Manometer

A

Device used to measure the pressure of a gas trapped in a container

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10
Q

Amonton’s Law (Gay-Lussac’s Law)

A

Pressure of a given number of moles of gas is directly proportional to its kelvin temperature when the volume is held constant

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11
Q

Absolute Zero

A

Temperature at which the volume of a gas would be zero according to Charles’s law

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12
Q

Charles’s Law

A

Volume of a given number of moles of gas is directly proportional to its kelvin temperature when the pressure is held constant

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13
Q

Boyle’s Law

A

Volume of a given number of moles of gas held at constant temperature is inversely proportional to the pressure under which it is measured

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14
Q

Avogardro’s Law

A

Volume of a gas at constant temperature and pressure is proportional to the number of gas molecules

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15
Q

Ideal Gas Law

A

Relation between the pressure, volume, amount, and temperature of a gas under conditions derived by combination of the simple gas laws

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16
Q

Ideal Gas Content (R)

A

Constant derived from the ideal gas equation R = 0.08206 L atm mol^-1K^-1 or 8.314 L kPa mol^-1K^-1

17
Q

Ideal Gas

A

Hypothetical gas whose physical properties are perfectly described by the gas laws

18
Q

Standard Conditions of Temperature and Pressure (STP)

A

273.15 K (0*C) and 1 atm (101.325 kPa)

19
Q

Standard Molar Volume

A

Volume of 1 mole of gas at STP, approximately 22.4 L for gases behaving ideally

20
Q

Partial Pressure

A

Pressure exerted by an individual gas in a mixture

21
Q

Dalton’s Law of Partial Pressures

A

Total pressure of a mixture of ideal gases is equal to the sum of the partial pressures of the component gases

22
Q

Mole Fraction (X)

A

Concentration unit defined as the ratio of the molar amount of a mixture component to the total number of moles of all mixture components

23
Q

Vapor Pressure of Water

A

Pressure exerted by water vapor in equilibrium with liquid water in a closed container at a specific temperature

24
Q

Mean Free Path

A

Average distance a molecule travels between collisions

25
Diffusion
Movement of an atom or molecule from a region of relatively high concentration to one of relatively low concentration (discussed in this chapter with regard to gaseous species, but applicable to species in any phase)
26
Rate of Diffusion
Amount of gas diffusing (through a given area over a given time)
27
Effusion
Transfer of gaseous atoms or molecules from a container to a vacuum through very small openings
28
Graham's Law of Effusion
Rates of diffusion and effusion of gases are inversely proportional to the square roots of their molecular masses
29
Kinetic Molecular Theory (KMT)
Theory based on simple principles and assumptions that effectively explains ideal gas behavior
30
Root Mean Square Speed
Measure of average speed for a group of particles calculated as the square root of the average squared speed
31
Compressibility Factor (Z)
Ratio of the experimentally measured molar volume for a gas to its molar volume as computed from the ideal gas equation
32
Van der Waals Equation
Modified version of the ideal gas equation containing additional terms to account for non-ideal gas behavior