Acid-Base Equilibria Flashcards

1
Q

Bronsted-Lowry Acid

A

Proton donor

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2
Q

Bronsted-Lowry Base

A

Proton acceptor

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3
Q

Conjugate Base

A

Substance formed when an acid loses a proton

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4
Q

Conjugate Acid

A

Substance formed when a base gains a proton

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5
Q

Acid Ionization

A

Reaction involving the transfer of a proton from an acid to water, yielding hydronium ions and the conjugate base of the acid

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6
Q

Base Ionization

A

Reaction involving the transfer of a proton from water to a base, yielding hydroxide ions and the conjugate acid of the base

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7
Q

Amphiprotic

A

Species that may either donate or accept a proton in a Bronsted-Lowry acid-base reaction

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8
Q

Amphoteric

A

Species that can act as either an acid or a base

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9
Q

Autoionization

A

Reaction between identical species yielding ionic products; for water, this reaction involves the transfer of protons to yield hydronium and hydroxide ions

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10
Q

Ion-Product Constant for Water (Kw)

A

Equilibrium constant for the autoionization of water

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11
Q

Neutral

A

Describes a solution in which [H3O+]=[OH-]

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12
Q

Acidic

A

A solution in which [H3O+]>[OH-]

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13
Q

Basic

A

A solution in which [H3O+]<[OH-]

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14
Q

pH

A

Logarithmic measure of the concentration of hydronium ions in a solution

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15
Q

pOH

A

Logarithmic measure of the concentration of hydroxide ions in a solution

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16
Q

Acid-Ionization Constant (Ka)

A

Equilibrium constant for an acid ionization reaction

17
Q

Percent Ionization

A

Ratio of the concentration of ionized acid to initial acid concentration expressed as a percentage

18
Q

Base-Ionization Constant (Kb)

A

Equilibrium constant for a base ionization reaction

19
Q

Leveling Effect

A

Observation that acid-base strength of solutes in a given solvent is limited to that of the solvent’s characteristic acid and base species (in water, hydronium and hydroxide ions, respectively)

20
Q

Oxyacids

A

Ternary compound with acidic properties, molecules of which contain an central nonmetallic atom bonded to one or more O atoms, at least one of which is bonded to an ionizable H atom

21
Q

Monoprotic Acids

A

Acid containing one ionizable hydrogen atom per molecule

22
Q

Diprotic Acids

A

Acid containing two ionizable hydrogen atoms per molecule

23
Q

Stepwise Ionization

A

Process in which a polyprotic acid is ionized by losing protons sequentially

24
Q

Tripotic Acid

A

Acid that contains three ionizable hydrogen atoms per molecule

25
Diprotic Base
Base capable of accepting two protons
26
Buffer
Mixture of appreciable amounts of a weak acid-base pair the pH of a buffer resists change when small amounts of acid or base are added
27
Buffer Capacity
Amount of an acid or base that can be added to a volume of a buffer solution before its pH changes significantly (usually by one pH unit)
28
Henderson-Hasselbalch Equation
Logarithmic version of the acid ionization constant expression, conveniently formatted for calculating the pH of buffer solutions
29
Titration Curve
Plot of some sample property (such as pH) versus volume of added titrant
30
Acid-Base Indicators
Weak acid or base whose conjugate partner imparts a different solution color; used in visual assessments of solution pH
31
Color Change Interval
Range in pH over which the color change of an indicator is observed