Acid-Base Equilibria Flashcards
Bronsted-Lowry Acid
Proton donor
Bronsted-Lowry Base
Proton acceptor
Conjugate Base
Substance formed when an acid loses a proton
Conjugate Acid
Substance formed when a base gains a proton
Acid Ionization
Reaction involving the transfer of a proton from an acid to water, yielding hydronium ions and the conjugate base of the acid
Base Ionization
Reaction involving the transfer of a proton from water to a base, yielding hydroxide ions and the conjugate acid of the base
Amphiprotic
Species that may either donate or accept a proton in a Bronsted-Lowry acid-base reaction
Amphoteric
Species that can act as either an acid or a base
Autoionization
Reaction between identical species yielding ionic products; for water, this reaction involves the transfer of protons to yield hydronium and hydroxide ions
Ion-Product Constant for Water (Kw)
Equilibrium constant for the autoionization of water
Neutral
Describes a solution in which [H3O+]=[OH-]
Acidic
A solution in which [H3O+]>[OH-]
Basic
A solution in which [H3O+]<[OH-]
pH
Logarithmic measure of the concentration of hydronium ions in a solution
pOH
Logarithmic measure of the concentration of hydroxide ions in a solution
Acid-Ionization Constant (Ka)
Equilibrium constant for an acid ionization reaction
Percent Ionization
Ratio of the concentration of ionized acid to initial acid concentration expressed as a percentage
Base-Ionization Constant (Kb)
Equilibrium constant for a base ionization reaction
Leveling Effect
Observation that acid-base strength of solutes in a given solvent is limited to that of the solvent’s characteristic acid and base species (in water, hydronium and hydroxide ions, respectively)
Oxyacids
Ternary compound with acidic properties, molecules of which contain an central nonmetallic atom bonded to one or more O atoms, at least one of which is bonded to an ionizable H atom
Monoprotic Acids
Acid containing one ionizable hydrogen atom per molecule
Diprotic Acids
Acid containing two ionizable hydrogen atoms per molecule
Stepwise Ionization
Process in which a polyprotic acid is ionized by losing protons sequentially
Tripotic Acid
Acid that contains three ionizable hydrogen atoms per molecule