Functional Groups Pt. 2 Flashcards

1
Q

A specific structural arrangement of atoms or bonds that imparts a characteristic reactivity to the molecule.

A

Functional Group

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2
Q

are collections of atoms that attach the carbon skeleton of an organic molecule and confer specific properties.

A

Functional groups

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3
Q

in biological molecules play an important role in the formation of molecules like DNA, proteins, carbohydrates, and lipids.

A

Functional groups

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4
Q

Functional groups include:

A

hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and
sulfhydryl.

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5
Q
  • Only carbon and hydrogen
  • All single bonds
A

alkanes

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6
Q

What should you call cyclic hydrocarbons made up of just single bonds?

A

Cycloalkanes

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7
Q

Natural source of alkanes

A
  • natural gas
  • petroleum
  • coal
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8
Q
  • Only carbon and hydrogen
  • A carbon to carbon double bond
A

alkenes

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9
Q

What should you call a molecule with two C=Cs?

A

diene

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10
Q

is used in welding torches because it burns at high temperature

A

Ethyne (acetylene)

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11
Q

Many alkynes are of biological interest

A
  • Capillin
  • Dactylyne
  • Ethinyl estradiol
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12
Q

is an antifungal agent found naturally

A

Capillin

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13
Q

is a marine natural product

A

Dactylyne

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14
Q

is a synthetic estrogen used in oral contraceptives

A

Ethinyl estradiol

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15
Q

is the simpest alkyne

A

acetylene

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16
Q

it is used in blow torches and as a precursor for the synthesis of more complex alkynes

A

acetylene

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17
Q

histrionicotoxin

A

which cna be isolated from South American frogs and is used on poison-tipped arrows by South American tribes

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18
Q

a halogen (F, Cl, Br, I) replaces the hydrogen of an alkane

A

alkyl halides

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19
Q

halogen

A

F, Cl, Br, I

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20
Q

In alkyl halides, a _____________ replaces the hydrogen of an alkane

A

halogen (F, Cl, Br, I)

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21
Q

uses of alkyl halides

A
  • dry cleaning solvents
  • degreasing solvents
  • paint stripper
  • synthetic intermediates in idustry and the lab
22
Q

sources of alkyl halides

A
  • reactins of alkaswith halogens
  • nature, for instance halomon
23
Q
  • Only one oxygen
  • Has an O-H group
  • Can classify as 1º/2º/3º according to position of O-H group on carbon skeleton
24
Q

Why are short-chain alcohols so soluble in water?

A

They can form hydrogen bonds with H2O molecules

25
Some Alcohols
- ethanol - adrenaline - pseudephidrine - glycerol - cholesterol
26
- Only one oxygen - Has an O-H group - The O-H group is directly attached to a benzene ring
phenols
27
The C6H5- group has a special name. What is it?
Phenyl
28
- Only one oxygen - Has a C=O group - C=O group is at the end of carbon chain, so is next door to a hydrogen atom
aldehydes
29
Aldehydes can be easily oxidised to form …?
Carboxylic acids
30
can be found in food
aldehydes
31
examples of aldehydes
- cinnamaldehyde - vanillin - citral -citronellal
32
the major component of cinnamon bark, is a common flavoring agent; odor of cinnamon
cinnamaldehyde
33
is the primary component of the extract of the vanilla bean.
vanillin
34
has the lemony odor characteristic of lemongrass
citral
35
gives the distinctive lemon odor to citronella candles, commonly used to repel mosquitoes
citronellal
36
- Only one oxygen - Has a C=O group - C=O group is not at the end of carbon chain, so is next door to 2 carbons
ketones
37
Ketones cannot easily be oxidised. Why not?
No hydrogen atom attached to the C=O group.
38
- Has 2 oxygens - Has O-H and C=O groups on the same carbon atom - This -COOH group has to be at the end of a carbon chain
carboxylic acids
39
examples pf carboxylic acids
- formic acid - acetic acid - citric acid - para-Aminobenzoic acid
40
- Has 2 oxygens - One oxygen is part of a C=O bond, the other is next door, sandwiched between two carbons
esters
41
This ester can be made by reacting ethanoic acid with a an alcohol. Name the alcohol, and name the ester.
Alcohol = methanol ester = methyl ethanoate
42
examples of esters
- methyl salicylate - ethyl butyrate - isobutyl propionate
43
oil of wintergreen
methyl salicylate
44
essence of pineapple
ethyl butyrate
45
essence of rum
isobutyl propionate
46
- Has 1 oxygen - No O-H or C=O group - The oxygen is sandwiched between two carbon atoms
ethers
47
Why do ethers have much lower boiling points than their isomeric alcohols?
No hydrogen bonds between ether molecules
48
are organic derivatives of ammonia
Amines
49
They are classified according to how many alkyl groups replace the hydrogens of ammonia
Amines
50
- Has 1 oxygen - C=O group - Contains a nitrogen
Amide
51