FINALS GROUP 5 Flashcards

1
Q

A colorless gas with a characteristic pungent smell. It dissolves in water to give a strongly alkaline solution

A

Ammonia

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2
Q

Any of a class of basic organic compounds derived from ammonia by replacement of hydrogen with one or more monovalent hydrocarbon radicals

A

Amines

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3
Q

Any organic compounds with a carbonyl group bonded to a nitrogen atom

A

Amides

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4
Q

A nonmetallic chemical elements with atomic number 7 that under standard conditions is a colorless, odorless, inert gas, that constitutes 78 percent of the Earth’s atmosphere

A

Nitrogen

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5
Q

The smallest part of a substance that cannot be broken down chemically

A

Atomic

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6
Q

Nitrogen came from the greek word ___ (latin) and ___ (greek) which means

Genes (greek) means

A

Nitrum
Nitron
Native soda
Forming

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7
Q

5th abundant element in the universe

Makes up 78% of earths atmosphere (approx. 4,000 trillion tons)

A

Nitrogen

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8
Q

Obtained through fractional distillation from liquefied air

A

Nitrogen

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9
Q

Cannot support living forms and combustion on its own

A

Nitrogen

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10
Q

Amines contain ___

A

Carbon hydrogen bonds

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11
Q

Larger amines are ___ while methylamine and ethylamine are ___ at room temperature

A

Liquids
Gases

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12
Q

___ amines are water soluble and ___ one are not so soluble

A

Smaller
Larger

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13
Q

Amines are found or used in ___, ___ and common ___

A

Dyes
Drugs
Animal toxins

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14
Q

Amines generally have a __ or __ as it is mostly formed during breakdown of animal cell proteins

A

Bad
Pungent odor

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15
Q

___ is an inorganic nitrogen containing chemical compound.

A

Ammonia

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16
Q

Ammonia gas which is toxic can be dissolved in water to form ___ that is commonly used in household and industrial cleaning products

A

Aqueous ammonia

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17
Q

Good smelling Amines are generally ___ some are potent ___ like ___

A

Toxic
Carcinogens
B-naphthylamine

18
Q

The structure of ___ is organic compounds with a carbonyl group bonded to a nitrogen atom

19
Q

One alkyl or aryl group attached to nitrogen (E.g. ethanamide)

A

Primary amides

20
Q

Two alkyl or aryl groups attached to nitrogen
(E.g., N-methyl ethanamide)

A

Secondary amides

21
Q

Three groups attached to nitrogen (N,N-dimethylrthanamide)

A

Tertiary amides

22
Q

PROPERTIES OF AMIDES
1. water soluble due to hydrogen bonding

  1. Less water-soluble; tend to be solid at room temperature
    - Have a NEUTRAL ODOR, unlike amines
  2. More stable than amines; they resist hydrolysis better under normal conditions
A

Smaller amides
Larger amides
Stability

23
Q

EXAMPLES

  1. (CH3CONH2) used as a solvent, in plasticizer and in the synthesis of organic compounds
  2. (HCONH2) Used in the preparation of adhesives and as a solvent for chemical reactions
  3. ((DMF) A widely used solvent in organic chemistry, especially in polymerization Processes
A

Acetamide
Formamide
N,N-Dimethylformamide

24
Q

___ in proteins are amides, linking amino acids together
- Used in drugs formulations, as solvents and in the synthesis of medicine

A

Peptide bonds

25
A synthetic polymer, contains amide bonds in its structure - used in some pesticide formulations
Nylon
26
Organic compounds containing a ring structure with at least one atom other than carbon (nitrogen, oxygen, sulfur)
Heterocyclic compounds
27
TYPES OF HETEROCYCLIC COMPOUNDS These compounds have a ring with alternating double bonds (aromaticity) and contain heteroatoms
Aromatic heterocycles
28
TYPES OF HETEROCYCLIC COMPOUNDS (C5H5N) Nitrogen containing ring, used in herbicides, insecticide and as a solvent
Pyridine
29
TYPES OF HETEROCYCLIC COMPOUNDS (C4H40) oxygen containing ring, used in the synthesis of drugs and in the production of plastics
Furan
30
TYPES OF HETEROCYCLIC COMPOUNDS (C3H3NS) contains both sulfur and nitrogen; found in some vitamins and medications
Thiazole
31
TYPES OF HETEROCYCLIC COMPOUNDS These compounds do not have aromaticity but contain heteroatoms in their ring structure
Non-aromatic heterocycles
32
TYPES OF HETEROCYCLIC COMPOUNDS (C5H11N) A nitrogen-containing compound found in alkaloids; used in the production of pesticides and pharmaceuticals
Piperidine
33
TYPES OF HETEROCYCLIC COMPOUNDS (C4H80) oxygen containing compound used as a solvent in chemical reactions
Tetrahydrofuran
34
TYPES OF HETEROCYCLIC COMPOUNDS (C4H9N0) Nitrogen and oxygen containing used in chemical industries and as a solvent
Morpholine
35
PROPERTIES OF HETEROCYCLIC COMPOUNDS Often have distinctive, often pleasant odors and are stable under various condition
Aromatic heterocycles
36
PROPERTIES OF HETEROCYCLIC COMPOUNDS Typically more reactive than aromatic ones and may participate in a wide range of chemical reactions
Non-aromatic heterocycles
37
PROPERTIES OF HETEROCYCLIC COMPOUNDS Many heterocycles are soluble in water and organic solvent, which makes them versatile in both biological industrial application
Solubility
38
Heterocyclic compounds like ___ and ___ are used in herbicides and insecticide
Pyridine Thiazole
39
Some heterocycles (Indole and pyrrole) are used in the production of ___ and ___
Dyes Pigment
40
Vitamins, hormones and other biologically significant molecules often contain _____ (Vitamin b12, nicotine)
Heterocyclic structure