Exam questions Flashcards

1
Q

Meaning of electronegativity

A

The ability of an atom to attract a pair of electrons in a covalent bond

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2
Q

How permanent dipole-dipole forces arise

A

The difference in electronegativity leads to bond polarity

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3
Q

What is meant by the term ionic lattice

A

Repeating pattern of oppositely charged ions

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4
Q

Why some molecules are polar

A

Molecule is non-symmetrical

Dipoles do not cancel out

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5
Q

What is a base

A

Substance which readily accepts h+ ions from an acid

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6
Q

What is an alkali

A

Releases OH- ions into an aqueous solution

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7
Q

What is ionic bonding

A

electrostatic attraction between oppositely charged ions

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8
Q

Anomalous properties of water

A

Ice lighter than water - open lattice in ice
HMP/BP - Strength of hydrogen bonds
High surface tension - the strength of H bonds spread across the surface

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9
Q

Properties of graphite

A

Giant covalent lattice
Good conductor - delocalised ELECTRONS
HBP - covalent bonds have to be broken
Soft - Van der waal forces

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10
Q

why ionic compounds cannot conduct when solid

A

Ions fixed in a lattice

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11
Q

Bond of Cl2 and C

A

Cl2 - Van der vaals

C - covalent bond

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12
Q

Why lalala has a lower first ionisation energy than lalala

A

Increase in energy shells as we go down
Increased shielding
Nuclear attraction decreases

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13
Q

Why second ionisation energy of oxygen has greater value than 1st ionisation energy

A

o+ ion smaller than O atom
More protons
Less electron-electron

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14
Q

Why 1st ionisation energies show a general increase across period 2

A

Increase in nuclear charge

The greater attraction between an electron and positive nucleus. more energy needed to break bond

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15
Q

Why first ionisation energy of lalala is less than that of lalala

A

lalala electron being removed at a higher energy shell

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16
Q

How to improve the standard situation practical

A

Rinse the weighing boat into flask after transferring solid
re-weigh weighing boat for precise mass
Dissolve solid in a beaker of water before transferring to to volumetric flask
Use a funnel to add solid
Use a pipette to add last few drops of distilled water

17
Q

What would happen if there is more of the powder thingy than expected in standard solution

A

Decrease mean titre volume
concentration higher
less would be needed to neutralise solution

18
Q

What does (V) represent in chloric(V) acid?

A

the oxidation number of chlorine

19
Q

Suggest why the enthalpy change of formation of C6H12O6 cannot be determined directly

A

Activation energy too high

20
Q

Use of alcohol

A

Solvent

Manufacture of Ester

21
Q

The reaction between nitrogen and oxygen in a car engine does not reach a dynamic equilibrium

A

Not a closed

22
Q

How does a reaction reach dynamic equilibrium

A

Rate of forward reaction slows down and rate of backward reaction speeds up
Útil rate of forward = rate of backwards

23
Q

How does infrared spec identify NO

A

Identifies functional group
Each pollutant has different spectrum
Can measure concentration of NO

24
Q

What is wrong with HCL

A

Forms acid rain

Corrosive

25
Q

How can HCL be removed

A

Use a Gad scrubber

React with a base

26
Q

what does cl2 and HOT sodium hydroxide make

A

3Cl2 + 6NaOH → NaClO3 + 5NaCl + 3H2O

27
Q

What does cl2 and dilute cold sodium hydroxide make

A

Cl2 + 2NaOH →NaClO + NaCl + H2O

28
Q

fluorine and water equation

A

2F2 + 2H2O Æ 4HF + O2