Atomic Structure and Isotope Flashcards
The relative mass of electrons
1/2000th
Order of scientists
Dalton
Thompson
Rutherford
Bhor
What did Dalton propose
All atoms are spheres. Each element is made of different spheres.
What did Thompson propose
Discovered electron. Atom wasn’t solid. Came up with plum pudding model.
What did Rutherford propose
Gold leaf experiment Discovered nucleus which was small and positively charged. Atom was mainly empty space made up of negative ‘cloud’
What did Bhor propose
The cloud of electrons would collapse on itself. Proposed electrons were in fixed energy shells.
Showed proof by showing when EM radiation is absorbed they move up energy shells.
Relative Isotopic Mass
Mass of an atom of an isotope compared to 1/12th of the mass of an atom of carbon-12
Relative Atomic Mass
The weighted mean mass of an atom of an element compared to 1/12th of the mass of an atom of carbon-12
What can mass spectrometry be used to do
provide structural information
Identify an unknown compound
Determine relative abundance of each isotope of an element
How do mass spectrometers work
Sample placed into mass spectrometer
Sample vaporised then ionised to form positive ions
Ions accelerated
Heavier ions move slower and difficult to deflect so ions of each isotope are separated
Ions detected on a mass spectrum as a mass: charge ratio
Each ion adds to the signal so the greater the abundance,the larger the signal.