Equillibrium Flashcards

1
Q

reversible reaction

A

a reaction that can proceed both the forward and reverse directions

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2
Q

equillibrium

A

when a chemical system reaches a point where there is no net observable change in the reactants and products

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3
Q

why is chemical equilibrium consdred dynamic?

A

the two processes are still occuring (forward and backward)

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4
Q

are the rates of the two processes the same at equillibrium?

A

YES

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5
Q

are the amounts of the reactants the same at equillibrium?

A

NOT neccesarily

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6
Q

what type of system can reached equillibrium?

A

a closed system

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7
Q

at a given temperature the point at which a system reaches equillibrium is constant

A
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8
Q

Le Chatelier’s Principle

A

when a stress is applied to a system at equilibrium, the equilibrium will shift (increase in speed) in the direction necessary to relive that stress

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9
Q

stress

A

a change in concentration, volume, pressure, temperature, or addition of an inert species

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10
Q

effect of increase of concentration on equilibrium

A

shift to use up the material

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11
Q

effect of decrease in concentration on equilibrium

A

shift to make more of the material

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12
Q

what is the effect of an increase in volume or decrease in pressure?

A

will shift ot the side with more gas molecules

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13
Q

what is the effect of a decrease in volume or increase in pressure on equillibrium in gasses?

A

will shift to the side with fewer gas molecules

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14
Q

what is the effect of an increase in temp

A

will shift to the side that uses thermal energy

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15
Q

what is the effect of a decrese in temperature on equilibrium?

A

will shift to the side that produces more thermal energy

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16
Q

what is the effect of adding a catalyst to eqilibrium?

A

no effect

17
Q

what is the effect of adding a solid on equilibrium?

A

no effect

18
Q

what is the effect of adding an inert gas at constant volume on equilibrium?

A

no effect

19
Q

what is the effect of adding an inert gas a constant pressure on equilibrium?

A

the volume will increase therefore will shift to the side with more gas molecules

20
Q

what does the equilibrium constant K eq mean?

A

equals the concentration of products over the concentration of reactants

21
Q

if Kew roughly equals one…

A

the reaction does not favour one side

22
Q

if Keq >1…

A

the reaction favours the products

23
Q

if K eq <1…

A

reaction favours the reactants

24
Q

percent reaction

A

a comparison of the yield of product at equilibrium and the maximum possible yield determined through stoichimetric calculations

25
Q

percent reaction <1

A

no reaction is said to occur

26
Q

percent reaction <50 %

A

reactants are favoured

27
Q

percent reaction > 50%

A

produces are favoured

28
Q

percent reaction >99%

A

reaction is said to go to completion

29
Q
A