Acid-Base Equilibrium Flashcards

1
Q

arrhenius acid theory

A

acids are substances that yield H+ ions (or H3O+ ions) as the only positice ions in solution

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2
Q

arrhenius bases definition

A

substances that yeild OH- ions as the only negative ion in solution

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3
Q

what is the bronsted-lowry definition acids

A

acids are proton H+ donors

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4
Q

what is the bronsted-lowry bases theory?

A

bases are proton H+ acceptors

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5
Q

what is the lewis acid definition

A

acids are electron pai acceptors

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6
Q

what is the lewis bases theory

A

are electron pair donors

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7
Q

conjugate acid

A

compound formed when a base gains a hydrogen ion

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8
Q

conjugate base

A

compound formed when an acid loses a hydrogen ion

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9
Q

strong acid

A

ionizes 100% in water to form hydronium ions and the anion of the acid

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10
Q

weak acid

A

ionizes less than 50% in water to form hydronium ions and the anion of the acids

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11
Q

strong base

A

metal hydroxides that DISSOCIATE completely in water to form hydroxide and metal ions

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12
Q

weak base

A

substances that react with water to form hydroxide ions and a cation

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13
Q

percent ionization

A

the degree to which a weak acid or base ionizes in water

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14
Q

autoionization of water

A

when water reacts with itself to form H3O+ and OH- ions

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15
Q

amphoteric/amphiprotic

A

substances that can act as an acid in one reaction but as a base in another

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16
Q

polyprotic acids

A

have more than 1 acidic hydrogen

17
Q

neutralization

A

combining an acid and a base to create a salt and water

18
Q

describe a salt

A

solid at room temperature composed of cations and anions and arranged in a crystal lattice

19
Q

what happens when a salt dissolves inw ater

A

they dissociate into aqueous solutions of ions that may or may not affect the pH of a solution

20
Q

what type of salt form neutral solutions?

A

cation of a strong base and anion of a strong acid

21
Q

what type of salts form acidic solutions?

A
  • salts where the cation is the conjugate acid of a weak base and the anion of a strong acid
  • salts where the cation is a highly charged metal ion and the anion is from a strong acid
  • non-metal oxides
22
Q

what type of salts form basic solutions

A
  • salts with the cation of a strong base and the anion of a weak acid
  • metal oxides
23
Q

what happens to pH when the cation is the conjugate acid of a weak base and anion is the conjugate base of the weak acid

A

the pH depends on the Ka of the conjugate acid and the Kb value of the conjugate base

24
Q

describe an acid base titration

A

a reaction between an acid and base resulting in the production of water and a salt (netutralization)

25
Q

indicator

A

something that changes colour at the end point

26
Q

end point

A

the point at which the indicator changes colour

27
Q

equivalence point or stochiometric point

A

when equal moles of H3O+ and OH- ions have reacted to produce water - neutralization is complete

28
Q

equivalence point pH of stron acid and base

A

at a pH of 7

29
Q

inflection point

A

where the equivalence point is on a titration curve - where the curve directoion changes

30
Q

what type of pH and salt is produced with a weak acid and a strong base - where is the equivalence point

A

produces a basic salt and equivalence point above pH of 7

31
Q

what type of salt does a strong acid and weak base produce and what is the pH of the equivalence point?

A

produces and acidic salta nd an equivalence point at a pH below 7

32
Q

midpoint of titration

A

the point at which half of the acid or base has been converted into its conjugate

33
Q

buffers

A

mixtures of conjugate acid-base pairs that allow a solution to resist changes in pH