Atomic Structure Flashcards

1
Q

what was the first atomic model and who proposed it?

A

solid sphere model, by Dalton

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2
Q

What was the second atomic model and who proposed it?

A

plum pudding model by JJ Thomson

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3
Q

what was the third atomic model and who proposed it?

A

the nuclear model by Rutherford

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4
Q

what was the fourth atomic model and who proposed it?

A

planetary model by Bohr

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5
Q

what was the fifth atomic model and who proposed it

A

the quantum model by Schrodinger

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6
Q

quantum mechanics

A

the study of motion at the atomic level where classical lawss of motions do not apply because the particles behave like waves

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7
Q

what did de Broglie think?

A

orginated the idea than an electron has both wave and particle properties

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8
Q

what demo did Schrodinger and de Broglie perform?

A

standing wave demo

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9
Q

What did Schrodinger and de Broglie find with the electron from hydrogen?

A

the model showed the electron as a circular stading wave ith wavelenths of whole number multiples

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10
Q

how did other orbits affect the standing wave?

A

would cause it to cancel out or collapse

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11
Q

orbital

A

a region around the nucleus where there is a high probability of finding an electron

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12
Q

what did the Schrodinger wave equation lead to?

A

can be used to calculate electron energy levels, which gives a definable amount of energy to an electron allowing it to be localized to a given orbital

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13
Q

Heisenbergs uncertainty principle

A

the idea that it is impossible to know the exact position and speed of an electron and the same given time

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14
Q

electrons are so small that any attempt to measure its location or speed will affect its location and/or speed

A
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15
Q

what are the two main points of the quantum mechanical model?

A
  • electrons can be in different orbitals by absorbing or emitting quanta of energy
  • the location of electron is given by a probability distribution
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16
Q

electron configuration

A

shows the specific placement of electrons within an energy level

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17
Q

sublevel of an energy level called:

A

orbital

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18
Q

how many electrons can orbital hold?

A

a maximum of 2

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19
Q

what are the 4 types of orbitals??

A

s, p, d, f,
(sharp, principal, diffuse, and fundamental)

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20
Q

how many s orbitals?

A

single

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21
Q

how many p orbitals?

A

groups of 3

22
Q

how many d orbitals?

A

groups of 5

23
Q

how many f orbitals?

A

groups of 7

24
Q

where are s orbitals found?

A

on every energy level

25
where are p orbitals found?
at energy level 2 and above
26
where are d orbitals found?
energy levels 3 and above
27
where are d orbitals found?
in energy levels 3 and above
28
where are f orbitals found?
levels 4 and above
29
in what order are electrons placed in energy levels?
from lowest enegy (closest to the nucleus) to highest energy
30
Pauli Exclusion principle
when 2 electrons are placed in the same orbital, these electrons will spin in different directions (one arrow points up and another points down)
31
Aufbau pinciple
lowest energy orbitals are filled first
32
Hund's rule
when there are multiple orbitals of equal energy, each orbitals gets a single elerctron before pairing up electrons
33
describe longhand configuration
writing the lowest energy level and orbital type and put the number of electrons as a superscript for the orabital then conitnue until all electrons have been accounted for
34
describe shorthand or noble gas configuration
use the closest noble gas with fewer electrons, place that symbol is square brackets and resume the configuration and continue until all electrons have been accounted for
35
what are the 2 stable electron configurations
a filled set or orbitals or a half filled set of orbitals
36
Which elements are exceptions to the rule?
Cr, Mo, Cu, Ag, Au
37
how does Cr differ from normalcy?
[Ar]4s13d5 NOT [Ar]4s23d4 since it is more stable and takes less energy for the 4s and 3d orbitals to be half filled
38
describe the electron configuration of negative ions
negative ions will gain enough electrons to fill the orbitals of their highest energy level. Non-metals make anions so they would be P orbitals that are the highest energy shells
39
40
describe the electron configuration of positive ions
will lose electrons from the highest avaible energy shell before it loses from the next shell down
41
quantum numbers
set of 4 numbers that describe an electron's location
42
whats the first number?
principal quantum number (n), the energy level the electron is in
43
what is the second quantum number
secondary quantum number (l), describes sublevel (orbital type) s= 0 p = 1 d = 2 f = 3 aka angular momentum quantum number
44
what is the third quantum number?
magnetic quantum number (m) descibes which orbital the sublevel electron is in
45
what is the fourth quantum number?
spin quantum number describes whether electron is spinning clockwise (+1/2) or counterclockwise (-1/2)
46
Who discovered the electron?
J.J Thomson Joseph john
47
How was the electron discovered?
With the cathode ray experiment. Electric current run through a glass tube a stream of negatively charged particles was emittey
48
Who discovered the nucleus?
Rutherford
49
How was the nucleus discovered?
With the gold foil experiment
50
Who discovered the neutron?
James Chadwick