Equilibrium Flashcards

1
Q

equilibrium

A

reached when the concentrations of reactants and products become constant

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2
Q

dynamic equilibrium

A

forward and backward reactions are still occurring

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3
Q

forward reaction

A

reaction from left to right (reactants to products)

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4
Q

backward reaction

A

reaction from right to left (products to reactants)

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5
Q

equilibrium in terms of forwards and backwards reactions

A

rate of forward reaction equal to rate of backward reaction

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6
Q

equilibrium is dynamic

A

reaction has not stopped but both forward and backward reactions are occurring at the same rate

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7
Q

equilibrium is achieved in a closed system

A

both reactants and products and react with each other no exchange of matter with surroundings

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8
Q

concentrations of reactants and products remain constant at equilibrium

A

they are being produced and destroyed at an equal rate

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9
Q

at equilibrium there is no change in macroscopic properties

A

color/density do not change because dependent on concentrations of mixture

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10
Q

equilibrium can be reached from either direction

A

same equilibrium mixture will result under same conditions can have all reacts, all products or mixture of both

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11
Q

equilibrium position

A

proportion of reactant and product in equilibrium mixture

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12
Q

equilibrium position lies to the right

A

mixture contains predominantly products

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13
Q

equilibrium position lies to the left

A

mixture contains predominantly reactants

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14
Q

equilibrium constant equation (Kc)

A
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15
Q

What does the magnitude of Kc tell you?

A

Kc > 1 reaction has very high conversion of reactants to products

Kc

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16
Q

reaction quotient

A

find Kc at equilibrium

17
Q

What does the magnitude of the quotient compared to the equilibrium constant tell us?

A

Q = Kc reaction is at equilibrium

Q

Q > Kc reaction proceeds to the left (favors reactants)

18
Q

What is Kc for an inverse reaction

A

1/Kc

19
Q

Kc for a multiple of a reaction

A

Kcx

20
Q

Kc when add two reactions

A

Kc1 + Kc2

21
Q

Le Chatelier’s principle

A

when a system at equilibrium is subjected to a change, it will respond in such a way as to minimize the effect of the change

22
Q

Effect of changing concentration on equilibrium (increase conc of reactants)

A
  • forward reaction rate increases
  • new concentrations of reactants/products
  • equilibrium shifts in favor of products
23
Q

effect of changing pressure on equilibrium position (increase pressure of reaction)

A
  • seeks to decrease pressure
  • shift in equilibrium position to favour side with smaller number of molecules
  • Kc will remain the same
24
Q

effect of changes in temperature on equilibrium position (decrease temperature)

A
  • produces heat
  • favours exothermic reaction
  • Kc will change depending on shift
  • to right will increase Kc
25
Q

effect of catalyst on equilibrium position

A
  • no change in position
  • just enables equilibrium to be achieved more quickly
  • Kc does not change value