Electron Configuration Flashcards

1
Q

period

A

row of periodic table

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2
Q

What does the period number correspond to?

A

principle energy level

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3
Q

group

A

column of periodic table

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4
Q

What does the group number correspond to?

A

number of electrons in valence level

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5
Q

What is electron configuration based on?

A

Quantum Mechanical Model

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6
Q

What will electrons in the ground state occupy?

A

lowest possible energy level

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7
Q

What can electrons only have?

A

specific energy levels

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8
Q

What is each energy level split into?

A

sublevels

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9
Q

Are all sublevels available at every energy level?

A

no

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10
Q

What are sublevel made up of?

A

a number of possible orbitals

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11
Q

What does each orbial have?

A

identical energy

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12
Q

How many possible orbitals does the s sublevel have?

A

1

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13
Q

How many possible orbitals does the p sublevel have?

A

3

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14
Q

How many possible orbitals does the d sublevel have?

A

5

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15
Q

How many possible orbitals does the f sublevel have?

A

7

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16
Q

What does each orbital represent?

A

a region in space with 90% chance of finding a specific electron

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17
Q

How many electrons can occupy any specific orbital?

A

maximum 2 electrons

18
Q

Describe the s sublevel.

A

1 orbital

spherical

19
Q

Desribe the p sublevel.

A

3 orbitals

dumbell shaped

20
Q

Aufbau principle

A

gives order of electron configuration

21
Q

Hund Rule

A

gives half fill identical orbitals then pair up electrons

22
Q

Pauli Exclusion

A

no 2 electrons can be identical

23
Q

What does Z = x mean?

A

atom has x electrons

24
Q

What must be done when drawing energy level diagrams for 3d and 4s?

A

Put overlap

25
Q

1st ionization energy

A

energy needed to remove 1 mol of electrons from 1 mol of atoms in gaseous state

removal of electron in highest energy level to infinity

26
Q

How can first ionization energy be calculated?

A

from wavelength or frequency of convergence limit

27
Q

successive energy level

A

energy needed to remove next mol of electrons then next and next

28
Q

What does the energy needed to remove specific electron depend on?

A

nuclear charge (higher charge, more attraction to nucleus)

distance from nucleus (further away, less attraction)

shielding (full sublevels shild outermost electron, less attraction)

29
Q

What are the two exceptions to the Aufbau Principle?

A

Cr [Ar] 4s1 3d5

Cu [Ar] 4s1 3d10

because s electron moves to d sublevel

more stable

30
Q

What is the convergence level shown to be?

A

wavelength = x

31
Q

convergence limit

A

where energy levels run out

32
Q

What is the formula for the first ionization energy?

A

E = hc/x

33
Q

What does the energy of photon correspond to?

A

first ionization energy

34
Q

uncertainty principle

A

cannot know where an electron is at any given moment in time but can work out where electron likely to be

35
Q
A
36
Q

atomic orbital

A

region around an atomic nucleus with a 90% probability of finding an electron

37
Q

Why can electrons occupy same region of space despite mutual repulsion?

A

spin in opposite directions

38
Q

electron configuration for Cr

A

Cr: [Ar] 3d5 4s1

39
Q

electron configuration for Cu

A

Cu: [Ar] 3d10 4s1

40
Q

Why do chromium and copper have different electron configurations?

A

half-full (or full) d sublevel relatively stable because minimizes electron repulsion with six singly occupied orbitals (or all orbitals filled)

41
Q

What is the equation for the first ionization energy of hydrogen?

A

H(g) -> H+ + e-