Equation - 2 Flashcards
Laboratory Preparation of HCl Gas
NaCl + H2SO4 (conc.) (<200°C) → NaHSO4 + HCl
Purification of HCl Gas
Pass the gas through conc. sulphuric acid.
Collection of HCl Gas
By upward displacement of air (gas is heavier than air and highly soluble in water).
Identification of HCl Gas
Glass rod dipped in ammonia solution forms thick white fumes.
Preparation of Hydrochloric Acid
HCl gas dissolved in water using a funnel arrangement.
Reaction of HCl with Active Metal
Zn + 2HCl → ZnCl2 + H2
Reaction of ZnO with HCl
ZnO + 2HCl → ZnCl2 + H2O
Reaction of HCl with a Base
Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Reaction of HCl with a Carbonate
NH4OH + HCl → NH4Cl + H2O
Reaction of HCl with Sodium Carbonate
Na2CO3 + HCl → 2NaCl + CO2
Reaction of HCl with Sodium Bicarbonate
NaHCO3 + HCl → NaCl + H2O + CO2
Reaction of HCl with Magnesium Sulphite
MgSO3 + HCl → MgCl2 + H2O + SO2
Reaction of HCl with Sodium Bisulphite
NaHSO3 + HCl → NaCl + H2O + SO2
Reaction of HCl with Silver Nitrate
AgNO3 + HCl → AgCl + HNO3
Reaction of HCl with Lead Nitrate
Pb(NO3)2 + 2HCl → PbCl2 + 2HNO3
Preparation of Aqua Regia
HCl + HNO3 (conc.) → NOCl + 2H2O + 2[Cl]
Laboratory Preparation of Ammonia
2NH4Cl + Ca(OH)2 → CaCl2 + 2H2O + 2NH3
Drying Agent for Ammonia
Quicklime (CaO)
Collection of Ammonia Gas
By downward displacement of air (lighter than air and highly soluble in water).
Preparation of Ammonia from NH4Cl
NH4Cl + NaOH → NaCl + H2O + NH3
Preparation of Ammonia from Ammonium Sulphate
(NH4)2SO4 + Ca(OH)2 → CaSO4 + 2H2O + 2NH3
Preparation of Ammonia from Metal Nitrides
Mg3N2 + 6H2O → 3Mg(OH)2 + 2NH3
Preparation of Ammonia from Calcium Nitride
Ca3N2 + 6H2O → 3Ca(OH)2 + 2NH3
Preparation of Ammonia from Aluminium Nitride
AlN + 3H2O → Al(OH)3 + NH3
Haber Process for Ammonia Manufacture
N2 + 3H2 → 2NH3 + Δ (450-500°C, Fe catalyst, Mo promoter)
Source of Nitrogen for Haber Process
Fractional distillation of liquid air.
Source of Hydrogen for Haber Process
Water gas (Bosch process).
Reactants in Haber Process
Nitrogen and hydrogen in 1:3 ratio.
Catalyst in Haber Process
Finely divided iron.
Promoter in Haber Process
Molybdenum.