Chemistry - Equations Flashcards
Action of Metals with Alkalis
Metal + Alkali → Salt + Hydrogen
Reaction of Zinc with Alkali
Zn + 2KOH → K₂ZnO₂ + H₂
Reaction of Aluminum with Alkali
2Al + 2NaOH + 2H₂O → 2NaAlO₂ + 3H₂
Reaction of Lead with Alkali
Pb + 2NaOH → Na₂PbO₂ + H₂
Reaction of Metal Oxides / Hydroxides with Alkalis
Metal oxide / Hydroxide + Alkali → Salt + Water
Reaction of ZnO with Alkali
ZnO + 2KOH → K₂ZnO₂ + H₂O
Reaction of PbO with Alkali
PbO + 2NaOH → Na₂PbO₂ + H₂O
Reaction of Al₂O₃ with Alkali
Al₂O₃ + 2NaOH → 2NaAlO₂ + 2H₂O
Reaction of Pb(OH)₂ with Alkali
Pb(OH)₂ + 2NaOH → Na₂PbO₂ + 2H₂O
Reaction of Al(OH)₃ with Alkali
Al(OH)₃ + NaOH → NaAlO₂ + 2H₂O
Electrolysis of Molten Lead Bromide
Occurs with graphite electrodes at molten state (above 380°C)
Electrolyte used in Electrolysis of PbBr₂
Electrolysis of molten lead bromide with graphite electrodes
(molten state above 380°C)
PbBr2 → Pb2+ + 2Br−
Reaction at anode [graphite]
2Br− → 2e− → Br2
Br + Br → Br2 (brown)
Reaction at cathode [graphite]
Pb2+ + 2e− → Pb
Reaction at Anode in PbBr₂ Electrolysis
2Br⁻ → 2e⁻ + Br₂ (brown gas)
Reaction at Cathode in PbBr₂ Electrolysis
Pb²⁺ + 2e⁻ → Pb (lead metal)
Electrolysis of Acidified Water
Uses platinum electrodes
Reaction at Anode in Electrolysis of Water
4OH⁻ − 4e⁻ → 2H₂O + O₂ (gas)
Reaction at Cathode in Electrolysis of Water
4H⁺ + 4e⁻ → 2H₂ (gas)
Electrolysis of Aqueous CuSO₄
Uses copper electrodes
Reaction at Anode in Electrolysis of CuSO₄
Cu → Cu²⁺ + 2e⁻
Reaction at Cathode in Electrolysis of CuSO₄
Cu²⁺ + 2e⁻ → Cu
Application of Electrolysis: Electroplating
Used for coating metals with a thin layer of another metal
Electrolyte used in Silver Plating
Na[Ag(CN)₂]
Reaction at Anode in Silver Plating
Ag → Ag⁺ + e⁻
Reaction at Cathode in Silver Plating
Ag⁺ + e⁻ → Ag (silver coating)
Electrolyte used in Nickel Plating
Aqueous NiSO₄
Reaction at Anode in Nickel Plating
Ni → Ni²⁺ + 2e⁻
Reaction at Cathode in Nickel Plating
Ni²⁺ + 2e⁻ → Ni (nickel coating)
Application of Electrolysis: Electro-Refining of Copper
Used to purify copper
Electrolyte used in Copper Refining
Aqueous CuSO₄
Reactions in Electro-Refining of Copper
CuSO₄ → Cu²⁺ + SO₄²⁻ and H₂O → H⁺ + OH⁻
Reaction at Anode in Copper Refining
Cu → Cu²⁺ + 2e⁻
Reaction at Cathode in Copper Refining
Cu²⁺ + 2e⁻ → Cu (pure copper deposited)