Electrochemistry Flashcards

1
Q

What are anodes?

A

Electrodes that electrons flow from

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2
Q

What are cathodes?

A

Electrodes that electrons flow into

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3
Q

What are anions?

A

Negatively charged ions

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4
Q

What are cations?

A

Positively charged ions

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5
Q

What is a standard half cell?

A

Defines the oxidisation/reduction capabilities of substances quantitatively

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6
Q

What is a strong oxidising agent?

A

A substance that brings about oxidation by being reduced and gaining electrons. They will have a large positive E value.

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7
Q

What is a strong reducing agent?

A

A substance that brings about reduction by being oxidised and losing electrons. They will have a large negative E value.

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8
Q

What is the trend in tendency to gain electrons?

A

The more positive the E value, the more likely the substance will gain electrons

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9
Q

What does a galvanic cell use?

A

a spontaneous redox reaction to produce electricity

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10
Q

What are salt bridges used for in a galvanic cell?

A

They connect two compartments chemically and help to maintain neutrality in the separate compartments to prevent ion migration.

They also complete the circuit to make a galvanic cell into an electrochemical cell.

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11
Q

What happens in an electrolytic cell?

A

A current is imposed on a system to drive a non-spontaneous redox reaction.

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12
Q

What is the use of a battery in an electrolytic cell?

A

Produces a current and acts as an electron pump.

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13
Q

What half reaction occurs at the cathode?

A

A reduction, requiring electrons

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14
Q

What half reaction occurs at the anode?

A

An oxidation, producing electrons

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15
Q

What does faraday’s law describe?

A

The relationship between the amount of elements disposited or gas liberated at an electrode due to current.

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16
Q

What can faraday’s law be used to calculate?

A

The amount of metal deposited on an electrode in a galvanic cell as the aqueous solution accepts electrons.

17
Q

What is the weight of product formed at the electrode proportional to?

A

the electrons transferrered

18
Q

What is a faraday?

A

A mole of electrons or 96500 coulombs

19
Q

What is a coulomb?

A

The amount of electricity transferred when a current of one ampere flows for one second.