electrlysis Flashcards

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1
Q

charge of the cathode

A

negative

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2
Q

charge of the anode

A

positive

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3
Q

What happens at the anode?

A

Non-metal ions are oxidised to the element at the anode.

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4
Q

What happens at the cathode?

A

Metal ions are reduced to the element at the cathode.

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5
Q

What does a solution need to be to be electrolysed?

A

A molten ionic compound. An ionic solid cannot be electrolysed as the ions are in fixed position and cannot move.

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6
Q

Why would electrolysis need to be used?

A

If a metal is too reactive to be reduced with carbon or reacts with carbon then electrolysis can be used to extract the metal.

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7
Q

Disadvantage of electroylsis.

A

Expensive lots of energy is needed to melt the compound and pass current through.

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8
Q

What other ions form in aqueous solutions.

A

OH- and H+

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9
Q

How do you determine what is produced at the cathode in the electrolysis of an aqueous solution?

A

If the metal that the ions form are more reactive than hydrogen, then hydrogen gas is produced. If the metal is less reactive than hydrogen a solid layer of pure metal is produced instead.

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10
Q

How do you determine what is produced at the anode in the electrolysis of an aqueous solution?

A

If OH- and halide ions are present, molecules of chlorine, bromine or iodine will be formed. If no halide ions are present then OH- ions are discharged and oxygen will be formed.

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11
Q

Half equation for OH- ions

A

4OH- -> O2 + 2H2O + 4e-

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