EL Flashcards

1
Q

What is nuclear fusion

A

the coming together of 2 nuclei to form a heavier element. Requires a large amount of energy to overcome repulsive forces. Common in the sun and larger stars.

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2
Q

ionic compounds definition

A

oppositely charged ions held together by electrostatic attractions

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3
Q

formula for these ions:
1. hydroxide ion
2. nitrate ion
3. ammonium ion
4. sulfate ion
5. carbonate ion

A
  1. OH-
  2. NO3-
  3. NH4+
  4. SO4 (2-)
  5. CO3 (2-)
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4
Q

why do most ionic compounds dissolve in water

A

because water molecules are polar, so they can attract the positive and negative ions and break up the structure.

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5
Q

definition of a polar molecule

A

uneven distribution in electron density due to the differences in electronegativity between atoms in a covalent bond

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6
Q

properties of an ionic compound

A

. conduct electricity when molten/ dissolved in solution as ions are free to move around
. high melting points due to strong electrostatic forces between oppositely charged ions

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7
Q

covalent bonding

A

shared outer electrons to obtain full outer shell. there are electrostatic forces of attraction between the shared electrons and positive nucleus.

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8
Q

dative covalent / coordinate bond

A

where one atom donates 2 electrons to an atom / ion to form a bond.

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9
Q

examples of giant covalent structures

A

diamond, graphite, silicon dioxide

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10
Q

why are graphite and diamond insoluble

A

because they have very strong covalent bonds that are hard to break.

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11
Q

why can graphite conduct electricity but diamond can’t

A

graphite: carbon is bonded 3 times, the 4th electron is part of the delocalised structure - this delocalised structure means free electrons are able to carry a charge

diamond: carbon is bonded 4 times, so there are no free electrons that are able to carry a charge

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12
Q

describe a metallic structure

A

positive metal ions are held together rigidly. the metal ions donate an electron to the sea of delocalised electrons. there is an electrostatic force of attraction between positive metal ions and the negative delocalised electrons

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13
Q

why are metals good thermal conductors

A

because the delocalised electrons can transfer kinetic energy

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14
Q

why are metals good electrical conductors

A

because the delocalised electrons can carry a charge and are mobile.

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15
Q

why do metals have high melting points

A

due to the strong electrostatic attractions between the delocalised electrons and the positive ions

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16
Q

generally for every lone pair, how many degrees do you reduce the bond angle by?

A

2.5

17
Q

2 bond pairs no lone pairs?
3 bond pairs no lone pairs?
4 bond pairs no lone pairs?

A

. linear = 180 deg.
. pyramidal = 120 deg.
. tetrahedral = 109.5 deg.

18
Q

what happens when an electron absorbs energy

A

gets excited to a higher energy level. eventually the electron will lose energy and move back down.

19
Q

emission spectrum

A

black background, coloured lines. shows frequency of light given out when electron moves down energy levels

20
Q

absorption spectrum

A

coloured background, black lines. electron absorbs the frequency of energy that is equal to the energy gap between shells

21
Q

equation for energy, frequency and wavelength

A

E = hv
E = energy
h = plancks constant
v = frequency

22
Q

test for ions (using flame test)

A

1) dip nichrome wire in conc. HCl
2) dip wire into solution
3) present wire to bunsen and observe colour changes

23
Q

what colours?
.Li +
.Na+
.K+
.Ca2+
.Ba2+
.Cu2+

A

. crimson
.yellow-orange
.lilac
.red
.green
.green-blue

24
Q

isotopes

A

elements that have the same number of protons but different number of neutrons

25
Q

relative atomic mass

A

weighted mean mass of an element compared to 1/12th of an atom of carbon-12

26
Q

how do you calculate percentage yield

A

( actual / theoretical )x 100

27
Q

how do you make a standard solution

A
  1. weigh the solid (make sure you use a plastic / glass weighing boat
  2. transfer solid to beaker using deionised water to maintain yield
  3. dissolve solid fully with deionised water
  4. transfer solution to volumetric flask
  5. use more deionised water to fill solution to the graduation line
  6. mix solution by shaking (ensure there is a lid)
28
Q

phenolphtalein what colour do acid and alkali turn?
methyl orange what colour do acid and alkali turn?

A
  1. acid - colourless | akali - pink
  2. acid - yellow | alkali - red
29
Q

ionisation energy

A

the minimum amount of energy required to remove one mole of electrons from one mole of atoms in the gaseous state

30
Q

factors affecting ionisation energy

A

.shielding - the more electron shells there are between outermost electrons and nucleus the easier it is to remove the electrons
.nuclear charge - the bigger the nuclear charge, the greater attraction there is between the nucleus and outermost electrons, means more energy is required to remove electrons
.atomic size - the larger the atom, the weaker the attraction is between the nucleus and outermost electrons - it is easier to remove electrons

31
Q

test for sulfates

A

add hcl to solution to remove any carbonates
then add barium chloride, a white precipitate should form

32
Q

test for ammonium compounds

A

add sodium hydroxide to solution. ammonia gas should be produced. then present damp red litmus paper in the test tube. should turn blue

33
Q

test for halides using silver nitrate

A

testing for chloride, bromide, iodide ions involves adding nitric acid and then silver nitrate solution.
. iodide = yellow precipitate forms
. chloride = white precipitate forms
. bromide = cream precipitate forms