DF Flashcards

1
Q

molar gas equation

A

volume / molar gas volume

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2
Q

at standard room temp and pressure 1 mole of any gas occupies…

A

24moldm^-3

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3
Q

ideal gas equation

A

pV = nRT
p = pressure in pascals
v = volume in m^-3
n = moles
R = gas constant
t = temp in kelvin

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4
Q

how do you measure the volume of a gas experimentally

A

measure amount of gas using a gas syringe, can’t be used if more than one type of gas is present. when the plunger doesn’t move any further the reaction has stopped and volume can be measured, be careful though as plunger may stop very quickly.

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5
Q

what is enthalpy change of a reaction and what units is it measured in?

A

heat change in a reaction at constant pressure, measured in kjmol^-1

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6
Q

what are standard conditions

A

temperature of 298k and 100kpa pressure and 1moldm^-3 concentration

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7
Q

endothermic vs exothermic reactions

A

endothermic = absorbs energy from surroundings.
exothermic = release energy to surroundings

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8
Q

what type of process is bond making?

A

exothermic as it releases energy

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9
Q

what type of process is bond breaking?

A

endothermic as it requires energy

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10
Q

standard enthalpy change of neutralisation

A

enthalpy change when when an acid and alkali react to form one mole of water under standard conditions

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11
Q

standard enthalpy change of combustion

A

enthalpy change when one mole of a substance is completely burned in oxygen to make CO2 and H20 under standard conditions

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12
Q

standard enthalpy change of formation

A

enthalpy change when one mole of a compound is formed from its elements in their standard states, under standard conditions

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13
Q

calorimetry practical

A

.a fuel is lit up and burned underneath a beaker of water - the fuel raises the temperature of water by a specific amount.
. the energy is transferred from the fuel to the water however some is lost to surroundings
. to prevent energy loss we can use a lid on the beaker.
. weigh the fuel before and after we burn it.

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14
Q

how do you calculate energy loss or gained

A

q = mc delta t

m= mass of water in g
c = specific heat capacity g^-1k^-1
t = temp in kelvin

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15
Q

define a catalyst

A

a substance that increases the rate of a reaction by providing an alternative pathway that has a lower activation energy. the catalyst is chemically unchanged at the end of a reaction

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16
Q

what is cracking

A

the process of breaking a longer chained hydrocarbon to shorter hydrocarbons

17
Q

heterogenous catalyst

A

catalyst that is in a different state to the reactants

18
Q

how can you increase rate of reaction using a heterogenous catalyst

A

increasing the surface area as more particles can react with the catalyst at the same time

19
Q

describe reactions that could occur on a heterogenous catalyst

A

.substances adsorb onto surface of catalysts
. the bonds in the reactants weaken and form radicals
. these radicals react to form new substances
. these substances desorb from the surface.

20
Q

define saturated

A

each carbon is bonded 4 times, eg in an alkane

21
Q

give an example of unsaturated

A

alkene

22
Q

what type of reaction can alkenes undergo

A

addition

23
Q

arenes/ aromatic compounds

A

organic molecules that contain a benzene ring

24
Q

aliphatic

A

non aromatic compounds (eg alkanes and alkenes)

25
Q

angle around each bond in an alkane

A

109.5 degrees

26
Q

homologous series

A

group of compounds that have the same functional group + general formula

27
Q

structural isomer

A

same molecular formula different structural formula

28
Q

E/Z and cis and trans?

A

E = opposite side | Z = same side
trans = opposite side when there’s no hydrogens | cis = same side when theres no hydrogens

29
Q

test for alkenes

A

adding bromine water to an alkene causes a colour change from brown-orange to colourless

30
Q

what are polymers made from

A

monomer units

31
Q

describe what happens when em radiation from the sun is absorbed by the earth

A

some of the radiation is re-emitted as infrared. some of the greenhouse gases absorb this infrared and re-emit them back to the earth - this is known as the greenhouse effect.

32
Q

problems of incomplete combustion

A

.carbon monoxide is poisonous but can be removed using a catalytic converter
.soot can cause breathing issues

33
Q

what is photochemical smog

A

it is formed when there is a mix of carbon particulates and ozone

34
Q

catalytic converters

A

mainly found in cars, they reduce the level of harmful pollutants by converting them into less harmful gases.