DF Flashcards
molar gas equation
volume / molar gas volume
at standard room temp and pressure 1 mole of any gas occupies…
24moldm^-3
ideal gas equation
pV = nRT
p = pressure in pascals
v = volume in m^-3
n = moles
R = gas constant
t = temp in kelvin
how do you measure the volume of a gas experimentally
measure amount of gas using a gas syringe, can’t be used if more than one type of gas is present. when the plunger doesn’t move any further the reaction has stopped and volume can be measured, be careful though as plunger may stop very quickly.
what is enthalpy change of a reaction and what units is it measured in?
heat change in a reaction at constant pressure, measured in kjmol^-1
what are standard conditions
temperature of 298k and 100kpa pressure and 1moldm^-3 concentration
endothermic vs exothermic reactions
endothermic = absorbs energy from surroundings.
exothermic = release energy to surroundings
what type of process is bond making?
exothermic as it releases energy
what type of process is bond breaking?
endothermic as it requires energy
standard enthalpy change of neutralisation
enthalpy change when when an acid and alkali react to form one mole of water under standard conditions
standard enthalpy change of combustion
enthalpy change when one mole of a substance is completely burned in oxygen to make CO2 and H20 under standard conditions
standard enthalpy change of formation
enthalpy change when one mole of a compound is formed from its elements in their standard states, under standard conditions
calorimetry practical
.a fuel is lit up and burned underneath a beaker of water - the fuel raises the temperature of water by a specific amount.
. the energy is transferred from the fuel to the water however some is lost to surroundings
. to prevent energy loss we can use a lid on the beaker.
. weigh the fuel before and after we burn it.
how do you calculate energy loss or gained
q = mc delta t
m= mass of water in g
c = specific heat capacity g^-1k^-1
t = temp in kelvin
define a catalyst
a substance that increases the rate of a reaction by providing an alternative pathway that has a lower activation energy. the catalyst is chemically unchanged at the end of a reaction
what is cracking
the process of breaking a longer chained hydrocarbon to shorter hydrocarbons
heterogenous catalyst
catalyst that is in a different state to the reactants
how can you increase rate of reaction using a heterogenous catalyst
increasing the surface area as more particles can react with the catalyst at the same time
describe reactions that could occur on a heterogenous catalyst
.substances adsorb onto surface of catalysts
. the bonds in the reactants weaken and form radicals
. these radicals react to form new substances
. these substances desorb from the surface.
define saturated
each carbon is bonded 4 times, eg in an alkane
give an example of unsaturated
alkene
what type of reaction can alkenes undergo
addition
arenes/ aromatic compounds
organic molecules that contain a benzene ring
aliphatic
non aromatic compounds (eg alkanes and alkenes)
angle around each bond in an alkane
109.5 degrees
homologous series
group of compounds that have the same functional group + general formula
structural isomer
same molecular formula different structural formula
E/Z and cis and trans?
E = opposite side | Z = same side
trans = opposite side when there’s no hydrogens | cis = same side when theres no hydrogens
test for alkenes
adding bromine water to an alkene causes a colour change from brown-orange to colourless
what are polymers made from
monomer units
describe what happens when em radiation from the sun is absorbed by the earth
some of the radiation is re-emitted as infrared. some of the greenhouse gases absorb this infrared and re-emit them back to the earth - this is known as the greenhouse effect.
problems of incomplete combustion
.carbon monoxide is poisonous but can be removed using a catalytic converter
.soot can cause breathing issues
what is photochemical smog
it is formed when there is a mix of carbon particulates and ozone
catalytic converters
mainly found in cars, they reduce the level of harmful pollutants by converting them into less harmful gases.