DF Flashcards
molar gas equation
volume / molar gas volume
at standard room temp and pressure 1 mole of any gas occupies…
24moldm^-3
ideal gas equation
pV = nRT
p = pressure in pascals
v = volume in m^-3
n = moles
R = gas constant
t = temp in kelvin
how do you measure the volume of a gas experimentally
measure amount of gas using a gas syringe, can’t be used if more than one type of gas is present. when the plunger doesn’t move any further the reaction has stopped and volume can be measured, be careful though as plunger may stop very quickly.
what is enthalpy change of a reaction and what units is it measured in?
heat change in a reaction at constant pressure, measured in kjmol^-1
what are standard conditions
temperature of 298k and 100kpa pressure and 1moldm^-3 concentration
endothermic vs exothermic reactions
endothermic = absorbs energy from surroundings.
exothermic = release energy to surroundings
what type of process is bond making?
exothermic as it releases energy
what type of process is bond breaking?
endothermic as it requires energy
standard enthalpy change of neutralisation
enthalpy change when when an acid and alkali react to form one mole of water under standard conditions
standard enthalpy change of combustion
enthalpy change when one mole of a substance is completely burned in oxygen to make CO2 and H20 under standard conditions
standard enthalpy change of formation
enthalpy change when one mole of a compound is formed from its elements in their standard states, under standard conditions
calorimetry practical
.a fuel is lit up and burned underneath a beaker of water - the fuel raises the temperature of water by a specific amount.
. the energy is transferred from the fuel to the water however some is lost to surroundings
. to prevent energy loss we can use a lid on the beaker.
. weigh the fuel before and after we burn it.
how do you calculate energy loss or gained
q = mc delta t
m= mass of water in g
c = specific heat capacity g^-1k^-1
t = temp in kelvin
define a catalyst
a substance that increases the rate of a reaction by providing an alternative pathway that has a lower activation energy. the catalyst is chemically unchanged at the end of a reaction