Dental Materials Flashcards
What is the difference between an adherent and an adherend? Give an example for each.
adherend = the surface/substrate being bonded to
e.g. enamel, dentine, alloy, ceramic
adherent = the substrate doing the bonding
e.g. CR, GIC, acrylic, ceramic
How do we usually bond ceramic to metal? What type of bond is this?
- Metal is heated (~1000degC) forming an oxide layer (black surface) which is ready to bond with ceramic
- Very strong chemical adhesion (oxide layer and ceramic)
How do we usually bond a ceramic crown to a tooth?
- Adhesive/primer on enamel/dentine
- Resin cement layer
- Silane layer (replaces metal primer)
- Ceramic crown
What is the most distinctive chemical in silane?
What type of bonding does silane use?
- Silicon
- Ester bond (silane esters)
How do we usually bond metal (e.g. gold) to resin cement?
Metal primer
What makes up the ‘glass’ component in GIC and what does it do?
Calcium and aluminium (derived from glass) act as the base in the GIC acid/base reaction
What is the MoA of metal primer?
Bifunctional (like an amphipathic molecule)
C= group bonds to resin and -O- containing groups bond to metal.
What is one way to improve the retention when using metal primer?
Sandblasting (NOTE: we don’t sandblast ceramic, but use hydrofluoric acid)
What is the difference between adhesive and cohesive failure?
Cohesive failure is within the material or adhesive layer. (e.g. within resin cement layer or CR layer)
Adhesive failure is failure between dissimilar materials.
(e.g. between CR and adhesive, or ceramic and cement.
How does dentine differ from superficial vs. closer to the pulp
Tubules are larger in diameter and in greater density/numbers
True or false: Tertiary dentine is spongier than primary/secondary dentine.
False, tertiary dentine is stiffer.
What toothwear pattern might someone with Class II Div 2 occlusion have?
Thin incisal edges that are difficult to restore.
What are TWO ways in which xerostomia may impact on restoration longevity?
- Increased caries risk
- Too dry/dessicated for GIC -> brittle
What are FOUR factors associated with cavity prep that may influence adhesion to tooth structure?
- “Wetness”, particularly on dentine
- Cavity size (resistance/retention)
- Smear layer, pellicle
- Foundation of bonding substrate (e.g. infected dentine)
What are the percentage (by weight) compositions of enamel?
- 97% HA
- 2% water
- 1% organic material (amelogenins)
What are the percentage (by weight) compositions of dentine?
- 70% HA
- 20% organic material (90% collagen)
- 10% water
What is the percentage mineral (HA) content of cementum?
45-50% HA
What is problematic about aprismatic enamel?
Etching aprismatic enamel leaves a relatively flat surface with little retentive features (ie. no keyhole structure) resulting in weak micromechanical adhesion.
Air from the triplex is a major source of moisture. How long do we have to spray it to purge the water?
10-15secs of air spray.
What are TWO examples of a hybrid zone/layer?
- GIC on dentine
- Adhesive resin and primer on dentine
Where specifically in the dentine do resin tags most commonly form, intertubular or intratubular dentine?
Intertubular dentine. This is the portion that gets demineralised by the etch.
Where would you find intratubular dentine?
Lining the dentinal tubule.
What does etch remove in dentine?
- Mineral (HA)
- non-collagenous proteins
(It leaves the collagen framework)
True or false: dessicating dentine after etching will cause the collagen framework to irreversibly collapse.
False, although collapsed collagen matrix forms hydrogen bonds with each other, these bonds are broken when primer is applied.
Why are we taught to dry but not dessicate dentine after using conditioner?
So it’s not too dry nor wet for the RMGIC/GIC.
What is the main component of primer?
HEMA
What is the MoA of wet bonding and why might this not work in real practice?
MoA: dentine partially dried, then acetone-based primer used to ‘chase’ the rest of the water out
Issue: Acetone evaporates before it can get to the water, leaving water behind to form water blisters in the hybrid layer that can block formation of resin tags, resulting in weaker bond.