CL 20- acids, bases and pH Flashcards
brønsted-lowry acid
definition
proton donor
brønsted-lowry base
definition
proton acceptor
conjugate base of ethanoic acid
CH₃COO⁻
dibasic acids
[HA] related to [H⁺]
[HA] = [H⁺] x2
so [H⁺] = [HA] / 2
ionic equation for calcium + hydrochloric acid
Ca₍ₛ₎ + 2H⁺₍ₐ₎ –> Ca²⁺₍ₐ₎ + H₂₍₉₎
the g for hydrogen turned into a 9 for some reason
ionic equation for calcium carbonate and sulfuric acid
CaCO₃₍ₛ₎ + 2H⁺₍ₐ₎ –> Ca²⁺₍ₐ₎ + CO₂₍₉₎ + H₂O₍ₗ₎
equation for the dissociation of ethanoic acid
CH₃COOH₍ₐ₎ –> CH₃COO⁻₍ₐ₎ + H⁺₍ₐ₎
relationship between Ka and pKa
pKa = -logKa
the lower the Ka value, the higher the pKa value
expression for the ionic product of water, Kw
Kw = [H⁺][OH⁻]
why does water have a pH of 7 at 298K?
[H⁺]=[OH⁻]
so Kw=[H⁺]²
what happens to the pH of water as temperature increases?
- pH decreases
- because water dissociates more
- [H⁺] and [OH⁻] increases
- Kw increases
2 approximations made to Ka expression
[H⁺]=[OH⁻]
[HA] at equilbrium = initial [HA]
steps for pH of mixtures question
- write an equation
- find moles of acid and base
- find which is in excess
- find the moles remaining of the excess reactant
- find conc of remaining moles
- calculate pH