Chemical Equilibrium Flashcards

1
Q

Equilibrium

A

When the forward reaction rate is equal to the reverse reaction rate

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2
Q

Law of Mass Action

A

The rate of a chemical reaction is proportional to the product of the concentrations of the reacting substances

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3
Q

If equilibrium constant is large

A

Equilibrium does not occur until the concentrations of the original reactants are small & those of the products large

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4
Q

If equilibrium constant is small

A

Equilibrium occurs almost at once & relatively little product is produced

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5
Q

Le Chateliers Principle

A

If a stress is placed upon a system in equilibrium, the equilibrium is displaced in the direction that counteracts the effect of the stress

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6
Q

Small value of acid dissociation constant

A

Concentration of un-ionized molecule must be relatively large compared with the ion concentrations

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7
Q

Large value for acid dissociation constant

A

Concentrations of ions are relatively large

The larger the value for ionizaton constant, the stronger the acid

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8
Q

Second Law of Thermodynamics

A

Entropy of the universe increases for any spontaneous process

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