Chemical Basis of Life Flashcards
Matter
Anything that has mass and occupies space
3 states of matter
solid, liquid, gas
Atoms
Fundamental building blocks of matter
Periodic Table
Tabular arrangement of chemical elements
Synthetic Elements
All above 92, plus 43 and 61
Four elements make up 96.1% of body mass:
Hydrogen (H), Oxygen (O), Carbon (C), and Nitrogen (N)
9 elements make up 3.9& of body mass:
Calcium (Ca), Phosphorus (P), Potassium (K), Sulfur (S), Sodium (Na), Chlorine (Cl), Magnesium (Mg), Iodine (I), Iron (Fe)
Subatomic Particles
Protons, neutrons, electrons
What is at the nucleus of an atom and what is in its orbit?
Proton & neutron at nucleus, electrons in orbit
Bohr’s Model of Atom
Electrons revolve around the nuclus in energy levels called orbits.
Orbitals
Regions of space around nucleus where electrons are likely to be found. Contained in energy levels.
Atomic Number
Number of protons in nucleus
Atomic mass
Average weight of atom (determined by # of protons & neutrons)
Number of neutrons in an atom
Atomic mass number - atomic number
Noble gases
They have full outermost shell
Octet Rule
Atoms will gain or lose electrons to have a full outer shell of 8e.
Valence
Number of electrons in the outermost shell
Isotopes
Different forms of atoms of the same element. # of neutrons is different
Radioactive Isotopes
Nuclei Unstable. Spontaneously break down into atoms of another element
Compound
Cluster of atoms held together by chemical bonds
Molecule vs Compound
Molecule is formed when two or more atoms join together chemically. Compound is a molecule that contains at least two different elements.
Chemical formulas; subscript meaning?
how many of that kind of atom
Structural formulas
Diagram showing how atoms are arranged
Types of chemical bonds
Ionic bond, covalent bond, hydrogen bond
Intra-molecular vs Inter-molecular bonds
Ionic & Covalent: Intra-molecular
Hydrogen: Inter-molecular
Ionic Bond
Electrons are transferred between atoms to form ions. Electrical attraction of opposite charges forms bond.
Usually outer shell almost empty or full.
Covalent Bond
Electrons are shared between atoms.
Usually outer shell hall-full.
Types of Covalent Bonds
Single bond, double bond, triple bond
Single Covalent Bond
One pair of electrons is shared
Double Covalent bond
Two pairs of electrons are shared
Triple Covalent bond
Three pairs of electrons are shared
Nonpolar Covalent Bonds
Electrons are shared equally
Polar Covalent Bonds
Electrons are not shared equally.
Electronegativity
An atom’s tendency to attract electrons to itself in a chemical bond
The most electronegative element
Fluorine
The least electronegative element
Francium
The —– the difference between atom electronegativity values, the more polar chemical bond formed between them. (greater or less?)
Greater
Ionic bonds happen between:
Metals and non-metals
Covalent bonds happen between:
Two non-metals OR metalloids and non-metals
Hydrophilic Molecules
Polar, ionic molecules.
Do hydrophilic molecules dissolve easily in water?
Yes.
Hydrogen bonds form between:
Hydrophilic molecules and water
Hydrophobic Molecules
Nonpolar molecules.
Water molecules cannot form hydrogen bonds.
Do hydrophobic molecules dissolve easily in water?
No.
Hydrogen bonding determines these properties of water:
Cohesion
Adhesion
Surface Tension
Moderation of Temp. Changes
Ice floating
Excellent Solvent
Water Properties: Cohesion
Tendency of molecules to stick to same type of molecule
Water Properties: Adhesion
Tendency of one type of molecule to stick to a different type of molecule (Ex: flow of water up a tree)
Water Properties: Surface Tension
The ability of the surface of a liquid to resist an external force, due to cohesive nature of its molecules
Water Properties: Moderating Temperature Changes
Water absorbs a lot of energy as it heats. Hydrogen bonds resist increase in movement - more energy needed to raise temp.
Water releases a lot of energy as it cools. Hydrogen bonds form, releasing heat.
Water Properties: Ice Floating
Ice H bonds are stable, while liquid H bonds constantly break & reform
Water properties: Solvent
Polar & ionic molecules dissolve easily in water
Definition of Molarity?
Measure of Concentration
Molarity Formula
Number of moles / Volume
What are the results of water dissociation?
Hydrogen & Hydroxide ions
In water at room temp, concentration of H+ is:
10^-7 moles/liter
Pure water pH is:
7
Acidic solutions contain more:
H+
Basic solutions contain more:
OH-
Acidic solutions’ pH level is:
Lower than 7
Basic solutions’ pH level is:
Higher than 7
Strong Acids
Acids that completely dissociate in solution
Weak Acids
Do not completely dissociate in solution, only partly
Acid & Base, which is H+ donor and which is acceptor?
Acid is donor, Base is acceptor
NaOH & Ammonia (NH3), which is strong and which is weak base?
NaOH strong, NH3 weak
Does salt have affect on H+ when dissolved in water?
No
what does pH measure?
H+ concentration
pH formula
-log(H+)
Examples of Acids
Hydrocloric Acid
Carbonic Acid
Acetic Acid
Examples of Bases
Bicarbonate ion (HCO3-) or Ammonia (NH3)
Buffer
A solution that can resist changes in pH
When pH increases, the ____ of the buffer ____ H+
acid, releases
When pH decreases, the ____ of the buffer ____ H+
Base, absorbs
What pH level human blood is kept at?
7.4
Chemical Reactions
Occur when chemical bonds are formed, rearranged, or broken
Chemical Reactions contain:
Reactants and product(s)
3 Patterns of Chemical Reactions
Synthesis reactions
Decomposition reactions
Exchange reactions
Synthesis Reactions
Atoms or molecules combine to form more complex molecule
Synthesis Reactions: Anabolic or Catabolic?
Anabolic
Decomposition Reactions
Molecule is broken down
Decomposition Reactions: Anabolic or Catabolic?
Catabolic
Exchange Reactions
Involve both synthesis and decomposition
Solutions definition
Homogeneous mixtures of components that may be gases, liquids, or solids.
Solute
Substance dissolved
Solvent
What is solute dissolved in, usually liquid
Mixtures: Suspension
Composed of solid and liquid mixed together
Mixtures: Colloids
Composed of solid and liquid, however solids are not visible
Emulsion
Mixture of two or more liquids where one is present as droplets distributed throughout
Emulsification
Large lipid globules are broken down
When electrons remain in a shell (orbit), does the atom gain or lose energy?
Neither