Chem302 Unit 1 Episodes 1-4 Flashcards

1
Q

Entropy def

A

Dispersal of energy at constant temp

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2
Q

Enthalpy def

A

Transfer of heat energy at constant p

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3
Q

Work def

A

Organized molecular motion

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4
Q

Gibbs free energy def

A

Energy available to do work

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5
Q

What type of rxn is more favorable

A

Exothermic

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6
Q

BP def

A

Temp which all liquids boil and break ALL IMFs

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7
Q

Normal BP def

A

Temp at pressure of 1 atm

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8
Q

How does increasing temp impact dissolution of solid solutes

A

Increases entropy

Solid disoolves

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9
Q

How does increasing temp impact dissolution of gas solute in solvent

A

Decreases entropy

Gas bubbles out of solution

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10
Q

How does increasing temp impact dissolution of liquid solutes

A

Not necessarily about temp, like dissolves like

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11
Q

All covalent solutes are …

A

Non electrolytes

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12
Q

Weak electrolyte

A

Less than 100 percent dissociation

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13
Q

Strong electrolyte

A

More than 100 percent dissociation

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14
Q

Non electrolyte

A

No dissociation at all

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15
Q

Vant Hoff factor formula

A

Moles particles in solution / moles formula units(usually 1) dissolved
Ex. Na cl = 2

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16
Q

Comparing heat of vapor ization is about comparing what?

A

IMFS!

17
Q

What impacts VP?

A

ONLY temperature!!

18
Q

Does adding water to a container affect VP and why?

A

IT DOES NOT AFFECT VP the vp would remain the SAME becuase VP is just the pressure exerted by a vapor that exists in EQUILIBRIUM with is liquid phase

19
Q

If temperature is the same for both containers what is the vapor pressure(VP) for both containers

A

The vapor pressure (VP) for both containers is the same1

20
Q

What does it mean if a solid sublimes

A

The pressure will be less than the VP so the solid will never reach equilibrium with the gas and the system will turn entirely into gas

21
Q

How does the energy shift in Exothermic reactions

A

The energy level goes from high to low

22
Q

If both in liquid phase a molecule with strong IMFS will have a lower H than…

A

Molecule with weaker IMFS

23
Q

The stronger the what ? The larger the H vap will be btwn phases

A

INTERmolecular forces(between)

24
Q

Water is NOT

A

Aqueous

25
Q

When we dissolve salt into solvent what is the sign of triangle H of lattice energy

A

Positive because it takes energy to break apart the salt

26
Q

Often LE is NEGATIVE because

A

We are FORMING a crystal