[CHEM] Unit 12- Equilibrium (eqm) Flashcards

1
Q

A completion reaction makes:

A

Gases or precipitates

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2
Q

At eqm, rates are:

A

Equal

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3
Q

T/F: At eqm, concentrations are equal

A

F: At eqm, concentrations are CONSTANT

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4
Q

Dynamic eqm is:

A

When the atoms don’t stop; total amounts don’t change, but the reactions are still occuring

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5
Q

What is chemical eqm:

A

Involves real chemical reactions; makes new formulas

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6
Q

Solution eqm only applies to ___ solutions

A

Saturated

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7
Q

At solution eqm, what rates are equal?

A

The rate of dissolving and the rate of crystallization

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8
Q

At solution eqm, if you raise the temp for a gas solute, what happens?

A

LESS gas is dissolved

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9
Q

At solution eqm, if you raise the temp for a solid solute, what happens?

A

More solute dissolves until a new eqm is reached

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10
Q

At phase eqm, what rates are equal?

A

Rate of freezing=rate of melting

Rate of evaporation/boiling= rate of condensation

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11
Q

What is AAA and what does it mean?

A

Add, Arrow, Away

If something is added/increased, the shift will point away

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12
Q

What is RAT and what does it mean?

A

Remove, Arrow, Towards

If something is removed/decreased, the shift will point towards it

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13
Q

(LeChat) What is a stress?

A

A change in temperature, pressure, or concentration

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14
Q

If you add something, where and why does the equilibrium shift?

A

Shifts away, and because it needs to use up the excess

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15
Q

If you remove something, where and why does the equilibrium shift?

A

Shifts toward, and because it needs to replace what is removed

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16
Q

When pressure is changed, what is the shift of the eqm based on?

A

How many moles of gas there are- BASED ON STATES OF MATTER AND COEFFICIENTS

17
Q

If pressure is increased, what side will the eqm shift to?

A

The side of lesser moles of gas

18
Q

If pressure is decreased, what side will the eqm sift to?

A

The side of greater moles of gas

19
Q

What is the common ion effect (adding)?

A

If you add a different solute that creates on of the ions in the reaction, it is like adding that ion they have in common.

For example, NaCl->(Na+)+(Cl-). You cannot simply add chloride ions, so you add HCL (aq). This will shift the eqm AWAY, and increase the amount of NaCl while decreasing the amount of Na+.

20
Q

What is the common ion effect (removing)?

A

If you add a different solute that would create an insoluble product with one of the ions in the reaction, it is like removing that ion.

This would shift the eqm towards the removal.